%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.64251255   -0.07295675   -3.31395971
 Au                 0.28867122    0.07637492   -1.16235893
 C                 -0.90442205    1.54405137   -4.14590052
 H                  0.05394714    2.06206337   -4.24323116
 H                 -1.34105084    1.39754264   -5.13940514
 H                 -1.57577908    2.16059189   -3.54146328
 C                 -2.29339265   -0.87948542   -3.35184650
 H                 -2.98673977   -0.31870564   -2.71834652
 H                 -2.68056816   -0.91262671   -4.37552446
 H                 -2.20963506   -1.89808182   -2.96202506
 C                  0.36533357   -1.03957224   -4.50824484
 H                  0.50136068   -2.05667106   -4.12965519
 H                 -0.12916149   -1.07772381   -5.48450701
 H                  1.34811526   -0.57179153   -4.61675615
 C                  1.11312035    0.19692577    0.74514828
 C                  0.67621976   -0.91899626    1.66148044
 H                  1.13240832   -1.85646384    1.32639346
 C                  1.97725430    1.15702549    1.11803728
 H                  2.29232660    1.92644353    0.41890994
 H                  2.43923193    1.24706252    2.10589073
 H                  2.29032446   -0.68127865    3.06960802
 H                  1.05290156   -1.63041167    3.66059807
 N                  1.27007720   -0.77828479    3.11413221
 N                  0.73909259    0.28496032    3.89792742
 H                  0.55175283    1.11514003    3.34219162
 C                 -0.28674610   -0.15319269    4.75266087
 O                 -0.39425623   -1.31853504    5.08519331
 O                 -1.02779022    0.87432824    5.13111696
 C                 -2.14448065    0.55099653    5.99989068
 H                 -1.78409846    0.06806974    6.90987262
 H                 -2.61209826    1.50751085    6.22528391
 H                 -2.83649236   -0.10692503    5.46973989
 H                 -0.37921966   -1.05260209    1.77592306

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



