%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.02422238   -0.12877091   -3.39043324
 Au                -0.06639945    0.14294821   -1.05256738
 C                 -1.37769013    0.64398904   -4.29496538
 H                 -1.38924572    1.71967958   -4.09679215
 H                 -1.27997429    0.47405455   -5.37231739
 H                 -2.31938747    0.21348925   -3.94245534
 C                 -0.00037355   -1.88348438   -3.93913571
 H                 -0.91087528   -2.36614705   -3.57209501
 H                  0.02947711   -1.94637602   -5.03206821
 H                  0.86489582   -2.40669188   -3.52184168
 C                  1.51794785    0.57449792   -4.19758851
 H                  2.41263943    0.09520743   -3.78991045
 H                  1.47982168    0.41313095   -5.27998841
 H                  1.57123539    1.64747094   -3.99197961
 C                 -0.16288571    0.36760662    1.01029333
 C                 -0.35093273   -0.93240313    1.77946791
 H                  0.41781738   -1.62580160    1.41185971
 C                 -0.08828048    1.56721029    1.60962386
 H                  0.06501427    2.47861676    1.03734828
 H                 -0.18085497    1.73029414    2.68323156
 N                 -0.85363178   -0.18637045    4.26947084
 C                 -2.30061580   -0.36695009    4.43981100
 H                 -2.51415280   -1.43590189    4.48072340
 H                 -2.60632098    0.11539010    5.36828477
 H                 -2.81794411    0.07495497    3.58932988
 C                 -0.01449380   -0.94101343    3.31270162
 H                 -0.02944271   -1.98638315    3.64290230
 C                  1.36119641   -0.38168860    3.61739344
 O                  2.43158934   -0.58709759    3.15699939
 O                  1.18312356    0.54635836    4.71885589
 C                 -0.10161653    0.56551248    5.00870877
 H                 -0.44988103    1.19703374    5.81769580
 H                 -1.29641457   -1.40251950    1.60639370

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



