%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.06318542   -0.09837250   -3.37092340
 Au                -0.09203656    0.12066110   -1.03080231
 C                 -1.48874691    0.33232583   -4.25754959
 H                 -1.75132678    1.37298500   -4.04608618
 H                 -1.36442110    0.20083236   -5.33750142
 H                 -2.29906913   -0.31122778   -3.90305099
 C                  0.45029353   -1.80230363   -3.94303225
 H                 -0.32140455   -2.49015394   -3.58552688
 H                  0.49333143   -1.84009359   -5.03672817
 H                  1.41458585   -2.11435400   -3.53148015
 C                  1.34409317    0.94604364   -4.17499616
 H                  2.32939973    0.68702659   -3.77678434
 H                  1.33806598    0.79120255   -5.25900237
 H                  1.14470458    1.99932172   -3.95778858
 C                 -0.28886085    0.28970017    1.02932873
 C                 -0.17670462   -1.02788672    1.78051903
 H                  0.73511165   -1.52888288    1.43475868
 C                 -0.58129836    1.45096275    1.63665443
 H                 -0.68264027    2.37723876    1.07684616
 H                 -0.76269129    1.56351697    2.70737423
 N                  1.19550703   -0.15731581    3.75763515
 C                  2.52339419   -0.27562175    3.15214387
 H                  2.45734345    0.04319148    2.10973747
 H                  3.21877987    0.36497967    3.69428113
 H                  2.84685440   -1.31635634    3.21211082
 C                  0.03440325   -0.96476377    3.33523596
 H                  0.19791018   -1.99295982    3.67930570
 C                 -1.06787622   -0.37978645    4.19509828
 O                 -2.22256098   -0.60624289    4.31081477
 O                 -0.42052014    0.62415923    5.03831264
 C                  0.84810335    0.66779584    4.69126523
 H                  1.50789112    1.37436403    5.18115686
 H                 -0.98402134   -1.69818561    1.57114113

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



