%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.30378249   -0.09735199   -2.93176885
 Au                -0.47555882    0.09742039   -0.71928552
 C                 -0.91984955   -0.77613485   -4.12311464
 H                 -1.79491980   -0.12085918   -4.15933287
 H                 -0.47947817   -0.84991055   -5.12294996
 H                 -1.23894252   -1.76870426   -3.79256056
 C                  1.76427847   -1.20002963   -3.10050481
 H                  1.50165447   -2.20524178   -2.75843934
 H                  2.09426843   -1.24534864   -4.14354416
 H                  2.57876947   -0.82054660   -2.47685981
 C                  0.84087807    1.48808346   -3.68993403
 H                  1.64598146    1.92339534   -3.09088616
 H                  1.19624962    1.32266770   -4.71246654
 H                 -0.00042229    2.18696788   -3.70676468
 C                 -1.11680990    0.25153896    1.24559720
 C                 -1.24076890   -1.03808308    2.05192317
 H                 -1.13459857   -1.88581600    1.36573808
 C                 -1.27718102    1.45834265    1.84593093
 H                 -1.16927145    2.38364211    1.28548094
 H                 -1.57770640    1.58948585    2.88675848
 C                  1.06011845    0.75319672    3.40741651
 C                  1.72283184    0.18204538    2.19582956
 N                  0.25784513   -0.13035492    3.89819121
 H                  1.29119828    1.70169062    3.87397176
 O                  1.20345069   -1.07336876    2.06496492
 O                  2.57459242    0.65696105    1.49782387
 C                 -0.53841249   -0.02951073    5.12392906
 H                 -0.40749979   -0.95049447    5.69463876
 H                 -0.19371377    0.82950495    5.69752314
 H                 -1.59107348    0.08099220    4.85499499
 C                  0.08107752   -1.21456908    2.91975757
 H                  0.12284313   -2.18023600    3.42001790
 H                 -2.11716461   -1.23265244    2.63413733

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



