%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.31326740   -0.04538061   -2.50173500
 Au                -0.55330099   -0.04805382   -0.27844255
 C                 -0.46431860   -1.32405990   -3.56535510
 H                 -1.54520671   -1.16034974   -3.60031109
 H                 -0.05600072   -1.27582759   -4.57992785
 H                 -0.27247649   -2.31474619   -3.14298133
 C                  2.11775063   -0.35040995   -2.65947068
 H                  2.37197296   -1.31709384   -2.21496367
 H                  2.40523379   -0.35675446   -3.71586327
 H                  2.67544035    0.43975149   -2.14775180
 C                  0.03762410    1.54219564   -3.38034710
 H                  0.53890104    2.34930957   -2.83858991
 H                  0.43310807    1.48630918   -4.39971603
 H                 -1.03405321    1.75703362   -3.41712742
 C                 -1.55601996   -0.01493148    1.55264321
 C                 -1.00566212   -0.60632304    2.84037419
 H                 -1.02012290   -1.70043876    2.74655388
 C                 -2.80046477    0.49058420    1.49527069
 H                 -3.21219267    0.91694821    0.58286980
 H                 -3.47037624    0.49309378    2.35572335
 C                  1.57559390    0.01763888    1.07147074
 C                  1.30298716    1.37502470    1.65098429
 N                  1.35989472   -0.86384999    2.02007177
 H                  2.23853478   -0.17203410    0.23850243
 O                  0.73805705    1.14485706    2.86995221
 O                  1.54755396    2.46053611    1.20033180
 C                  1.49469122   -2.30800610    1.88428579
 H                  0.60514163   -2.70723013    1.38052138
 H                  2.37984012   -2.52695357    1.28615356
 H                  1.59384538   -2.75248118    2.87538001
 C                  0.50854839   -0.25073556    3.04953965
 H                  0.85018626   -0.54628824    4.04114948
 H                 -1.53853874   -0.35734718    3.73421619

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



