%nprocshared=24
%mem=41GB
#p opt=(calcfc,maxstep=6) freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt calcfc freq

1 1
 P                  0.11475173   -0.11171096   -3.38011678
 Au                -0.13527301    0.11301520   -1.04785430
 C                 -1.40235080    0.26449461   -4.34643312
 H                 -1.71784746    1.29196914   -4.14369470
 H                 -1.21112957    0.14738421   -5.41827753
 H                 -2.20475708   -0.41457527   -4.04414047
 C                  0.58918041   -1.80076650   -3.92739052
 H                 -0.17720053   -2.51429205   -3.61131881
 H                  0.68945597   -1.83432057   -5.01721328
 H                  1.54074456   -2.08029687   -3.46604219
 C                  1.39901041    0.97785222   -4.11614092
 H                  2.36864056    0.75861158   -3.65980914
 H                  1.46144281    0.81728663   -5.19754903
 H                  1.14678674    2.02358786   -3.91816065
 C                 -0.36536192    0.32372066    1.00494655
 C                 -0.12485024   -0.93665869    1.80470736
 H                  0.74978384   -1.47516772    1.42434093
 C                 -0.72829238    1.48517892    1.57067178
 H                 -0.91649214    2.37691782    0.97887573
 H                 -0.88312751    1.63207706    2.64195553
 N                  1.20202289   -0.11355038    3.83546053
 C                  2.55864385   -0.12123578    3.28099586
 H                  2.48357672    0.20029181    2.23948911
 H                  3.16494871    0.57154254    3.86233901
 H                  2.94559221   -1.13986208    3.34162912
 C                  0.11147280   -0.98714405    3.38932501
 H                  0.33979973   -1.99434939    3.76234413
 C                 -1.02439388   -0.43382934    4.20277449
 O                 -2.17893621   -0.66803699    4.28439334
 O                 -0.39559632    0.58035186    5.05799543
 N                  0.89384676    0.69650847    4.75050645
 H                 -0.96810249   -1.62823898    1.68585529

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



