%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.36385840   -0.06373498   -2.90134827
 Au                -0.52851262    0.07151826   -0.72929093
 C                 -0.64697820   -1.02059545   -4.10082136
 H                 -1.63004681   -0.55209506   -4.20390939
 H                 -0.15359692   -1.05025069   -5.07802014
 H                 -0.78186567   -2.04103398   -3.73082856
 C                  2.01889502   -0.86008214   -2.96358615
 H                  1.94676679   -1.88091103   -2.57725850
 H                  2.39316800   -0.88535858   -3.99222531
 H                  2.71581166   -0.29713072   -2.33602734
 C                  0.61468508    1.56380544   -3.71683435
 H                  1.28963273    2.17415379   -3.10988049
 H                  1.04457209    1.42935195   -4.71489789
 H                 -0.34540510    2.08083415   -3.80097159
 C                 -1.23955609    0.20232564    1.21438473
 C                 -1.25934797   -1.07217094    2.03898878
 H                 -1.03132119   -1.93617181    1.41286988
 C                 -1.49953810    1.38739964    1.80494173
 H                 -1.47268743    2.31615969    1.24050862
 H                 -1.77395950    1.50270902    2.85509716
 C                  1.25883610    0.68691639    3.49835440
 C                  1.86116942    0.16566861    2.26843846
 N                  0.26087946   -0.08072450    3.81677398
 H                  1.59849874    1.51256580    4.10600016
 N                  0.07701161   -1.11674614    2.92540180
 O                  1.13797726   -0.99211419    2.01527872
 O                  2.78347721    0.53208828    1.59484471
 C                 -0.58050172   -0.00457468    5.02402506
 H                 -0.54791966   -0.97623018    5.51577594
 H                 -0.16784047    0.77494373    5.66172822
 H                 -1.60406291    0.22908609    4.73539607
 H                 -2.08797821   -1.32419347    2.66728535

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



