%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.36381804    0.05442035   -4.39927099
 Au                -0.20152465    0.19515354   -2.04479473
 C                 -2.05945089   -0.29521267   -5.00857026
 H                 -2.73548211    0.50073022   -4.68363455
 H                 -2.06460229   -0.35336219   -6.10174246
 H                 -2.40722954   -1.24473032   -4.59211374
 C                  0.68322179   -1.27178003   -5.11548650
 H                  0.38168416   -2.23731867   -4.69999855
 H                  0.57521575   -1.29250682   -6.20479248
 H                  1.72968598   -1.08895027   -4.85617006
 C                  0.14863026    1.58746651   -5.26775892
 H                  1.18618341    1.82017815   -5.01178679
 H                  0.06104630    1.45805678   -6.35128999
 H                 -0.48776101    2.41738547   -4.94775932
 C                 -0.05660641    0.32034056   -0.01692373
 C                 -0.54408994   -0.77361404    0.85819985
 H                 -1.01192495   -1.56298425    0.26237331
 C                  0.82172343    1.30234361    0.61092140
 H                  1.19843858    2.07158221   -0.06261936
 H                  0.47699933    1.74421712    1.55027347
 C                 -1.45887690   -0.44348691    2.03484329
 C                 -2.04392037    0.82139724    2.18702768
 C                 -1.78483011   -1.45041242    2.95574224
 C                 -2.89511780    1.08659157    3.26235943
 H                 -1.84968800    1.60642023    1.46264048
 C                 -2.63431662   -1.18549392    4.03027566
 H                 -1.38404042   -2.45349048    2.83688660
 C                 -3.18433749    0.08838681    4.19395859
 H                 -3.33505561    2.07434289    3.36459158
 H                 -2.86811038   -1.97705883    4.73620536
 H                 -3.84409561    0.29559536    5.03126216
 C                  2.11146405    0.37080547    1.13412192
 C                  2.47603337   -0.62402946    0.03660688
 N                  1.64546297   -0.50675736    2.14013976
 H                  2.90754350    1.05466749    1.42094528
 O                  1.69086932   -1.72578307    0.26012544
 O                  3.24328864   -0.52812997   -0.88120306
 C                  0.86747703   -1.43860806    1.40771827
 H                  0.64924936   -2.36141309    1.94052797
 C                  1.31529690   -0.05242674    3.49862202
 C                  1.85104722    1.14057081    3.98462599
 C                  0.46634575   -0.81390811    4.30172612
 C                  1.53840003    1.57157156    5.27370001
 H                  2.52092440    1.74029052    3.35150467
 C                  0.15271885   -0.38241779    5.59085922
 H                  0.04386095   -1.75411159    3.91877307
 C                  0.68868067    0.81004310    6.07698573
 H                  1.96114552    2.51157697    5.65707005
 H                 -0.51699721   -0.98281176    6.22369545
 H                  0.44226637    1.15010337    7.09332000

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



