%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                 -0.51712740    0.11768715   -4.23400443
 Au                 0.33574229    0.25841362   -2.04300700
 C                 -1.70869635    1.44935110   -4.66705131
 H                 -1.21592904    2.42166925   -4.57597950
 H                 -2.07241279    1.32093093   -5.69190842
 H                 -2.55455506    1.41990359   -3.97419984
 C                 -1.43676613   -1.43680684   -4.57825979
 H                 -2.27214938   -1.52739239   -3.87781377
 H                 -1.82023904   -1.43907085   -5.60407228
 H                 -0.76940037   -2.29218025   -4.43850730
 C                  0.74579566    0.19823471   -5.56661086
 H                  1.45234392   -0.62855427   -5.44997762
 H                  0.26890080    0.13337154   -6.55019945
 H                  1.29490329    1.14115518   -5.49066683
 C                  1.06823883    0.37557852   -0.10267288
 C                  0.65574526   -0.77907508    0.79934746
 H                  0.89765244   -1.70180924    0.25441026
 C                  1.82446160    1.40092948    0.32229124
 H                  2.12021036    2.20370237   -0.34834185
 H                  2.18845392    1.52124159    1.34250418
 C                 -0.84498848   -0.82436625    1.09487300
 C                 -1.63766905    0.32925092    1.02766058
 C                 -1.44745485   -2.03825938    1.45512204
 C                 -3.00121309    0.27233629    1.32746420
 H                 -1.18314263    1.27098472    0.73763159
 C                 -2.80901585   -2.09714973    1.75694821
 H                 -0.85079793   -2.94756815    1.49433453
 C                 -3.59009299   -0.93922315    1.69570859
 H                 -3.60123290    1.17631667    1.27167902
 H                 -3.25956760   -3.04620455    2.03307848
 H                 -4.65010693   -0.98348685    1.92862597
 N                  1.40450131   -0.04749105    3.23112353
 C                  1.47459389   -1.01851054    2.11700768
 H                  1.15697309   -1.98488295    2.52602505
 C                  2.96980180   -1.08926534    1.87710776
 O                  3.63064416   -1.68492462    1.09712444
 O                  3.57921141   -0.23900762    2.88303139
 C                  2.60233332    0.28497301    3.59443294
 H                  2.84587788    0.95258839    4.41268903
 C                  0.16653611    0.36866165    3.90577833
 C                 -0.92569193   -0.49793599    3.95595683
 C                  0.08381972    1.62981664    4.49585817
 C                 -2.10056365   -0.10312496    4.59550543
 H                 -0.86042670   -1.49184348    3.48998457
 C                 -1.09099890    2.02452245    5.13649724
 H                  0.94463206    2.31288809    4.45655760
 C                 -2.18316846    1.15836819    5.18629136
 H                 -2.96172708   -0.78589097    4.63455202
 H                 -1.15578598    3.01878966    5.60201800
 H                 -3.10959666    1.46941984    5.69054725

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



