%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.73542924   -0.04972372   -3.78494702
 Au                 0.28490712    0.47795851   -1.53398775
 C                 -0.35492034    0.82301992   -4.98058799
 H                 -0.22555741    1.90348253   -4.86877459
 H                 -0.11102456    0.53187533   -6.00761918
 H                 -1.39842307    0.57251718   -4.76892073
 C                  0.52288750   -1.82876899   -4.19770172
 H                 -0.50326856   -2.13410293   -3.97355670
 H                  0.73171119   -2.00492681   -5.25827336
 H                  1.20666775   -2.42794462   -3.58938982
 C                  2.43653988    0.34331275   -4.35923587
 H                  3.16215624   -0.21636740   -3.76196665
 H                  2.55392468    0.07871883   -5.41530993
 H                  2.62709804    1.41253538   -4.22969744
 C                 -0.17546587    0.94299310    0.43660948
 C                 -0.71077226   -0.22622679    1.24856577
 H                 -0.02001300   -1.06668176    1.11275944
 C                 -0.09321969    2.19101420    0.92504973
 H                  0.26806470    3.01772551    0.31869610
 H                 -0.39461928    2.48489826    1.93242413
 C                 -2.07627986   -0.71309343    0.76485335
 C                 -3.05923989    0.18940873    0.33932881
 C                 -2.35699835   -2.08568567    0.74566118
 C                 -4.30114252   -0.27439049   -0.09781551
 H                 -2.84500536    1.25303267    0.34431540
 C                 -3.59844137   -2.55147905    0.30787153
 H                 -1.59885250   -2.79640351    1.06835107
 C                 -4.57383923   -1.64504851   -0.11595004
 H                 -5.05498003    0.43570173   -0.42611849
 H                 -3.80016081   -3.61886412    0.29343161
 H                 -5.53942923   -2.00480977   -0.46002819
 N                  0.53672822    0.29141628    3.42241831
 C                 -0.75717608   -0.06850257    2.81018849
 H                 -1.06520187   -1.03694818    3.22193944
 C                 -1.67474979    0.97910983    3.40780746
 O                 -2.82857979    1.21358622    3.29979419
 O                 -0.84137827    1.75946039    4.32133480
 C                  0.38393681    1.28767956    4.23314510
 H                  1.17299435    1.74901586    4.81547605
 C                  1.80161381   -0.38385757    3.09842806
 C                  2.94373813    0.36885852    2.82376111
 C                  1.86005753   -1.77707733    3.06569946
 C                  4.14382750   -0.27157626    2.51578293
 H                  2.89714552    1.46723887    2.84889127
 C                  3.06067646   -2.41787425    2.75861091
 H                  0.96002404   -2.37049161    3.28232870
 C                  4.20245127   -1.66539828    2.48353417
 H                  5.04395034    0.32166357    2.29866111
 H                  3.10655800   -3.51638580    2.73328319
 H                  5.14880475   -2.17013668    2.24073679

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



