%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                  0.30343613    1.35432684   -1.63696403
 C                  1.18273415    0.36999858   -0.77510261
 H                  2.19697733    0.26367619   -1.15561437
 C                 -1.14902113    1.36856112   -1.29380681
 H                 -1.93115632    1.15365279   -2.01014059
 C                  0.58513473   -0.90797839   -0.27388089
 C                  0.09534494   -1.87440246   -1.16260297
 C                  0.55419614   -1.17019544    1.10105415
 C                 -0.40981747   -3.08441560   -0.68485813
 H                  0.10925407   -1.67025493   -2.23048950
 C                  0.04834836   -2.37979897    1.58189450
 H                  0.91435082   -0.41098243    1.78811532
 C                 -0.43590629   -3.33996786    0.69015308
 H                 -0.78543352   -3.82782938   -1.38317695
 H                  0.02831433   -2.56979353    2.65170158
 H                 -0.83284297   -4.28009317    1.06299369
 N                 -0.15972298    1.91257824    0.71959668
 C                 -0.09792437    3.17679681    1.46016626
 H                  0.00997011    4.03818306    0.78443226
 H                 -1.01884817    3.29310667    2.03683056
 H                  0.74605298    3.16014801    2.15608460
 C                  0.94288800    1.67388961   -0.15656217
 H                  1.74961470    2.39713507   -0.10816840
 C                 -1.35178387    1.66762559    0.00001720
 H                 -2.29315031    1.73082002    0.53434849
 H                  0.61918192    2.20754500   -2.26113889

C H N 0
6-31G(d)
****


