%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

1 1
 P                 -0.34979647   -0.14098726   -3.63235008
 Au                 0.02338051    0.06579227   -1.32839144
 C                 -0.55228095    1.42806321   -4.56501584
 H                  0.33066400    2.05350828   -4.41188614
 H                 -0.66850340    1.20919288   -5.63030867
 H                 -1.43346412    1.95895630   -4.19697905
 C                 -1.84147655   -1.11874545   -4.07418553
 H                 -2.73666739   -0.59964477   -3.71909632
 H                 -1.89591361   -1.23974292   -5.16037268
 H                 -1.79954613   -2.10210282   -3.59658755
 C                  1.02639721   -0.99539114   -4.50147964
 H                  1.25030597   -1.94248512   -4.00346938
 H                  0.74735104   -1.18122625   -5.54383666
 H                  1.92258827   -0.36936061   -4.47396614
 C                  0.42336515    0.21465569    0.73618787
 C                 -0.09376834   -0.81358324    1.73959335
 H                 -0.51079546   -1.69913402    1.25987892
 C                  0.70932714    1.61435694    1.31872732
 H                  1.13661082    2.30094766    0.57787623
 H                 -0.17631662    2.11213782    1.72796089
 C                 -0.73917263   -0.49241217    3.05538051
 C                 -1.78622528    0.43739826    3.10926010
 C                 -0.34002603   -1.13396726    4.23721890
 C                 -2.41291504    0.73358402    4.32165622
 H                 -2.10757628    0.92256648    2.19161504
 C                 -0.96332925   -0.83823651    5.45116964
 H                  0.45180958   -1.87748386    4.19856317
 C                 -1.99689917    0.10169501    5.49595958
 H                 -3.22258860    1.45713993    4.34937767
 H                 -0.64551200   -1.34121757    6.35992984
 H                 -2.47948782    0.33502526    6.44016719
 N                  2.11793850    0.16392241    2.43215111
 C                  3.13674355   -0.38057798    3.33318189
 H                  3.84185328   -0.96151222    2.73638359
 H                  3.65119496    0.43657749    3.83666421
 H                  2.65356061   -1.03324750    4.06376494
 C                  1.39755470   -0.69663332    1.49401297
 H                  1.99765736   -1.50673720    1.09568543
 C                  1.72378205    1.39134994    2.38599549
 H                  2.12063333    2.12826927    3.07577554

C H P N 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD




