%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) nosymm scf=maxcyc=512

Opt freq

1 1
 P                  0.96230000    0.31940200   -2.99745400
 Au                 0.61193000   -0.50207100   -0.81828200
 C                  0.29294800    2.01768000   -3.18990800
 H                  0.80043200    2.68838600   -2.49065500
 H                  0.44071900    2.37637000   -4.21351700
 H                 -0.77515400    2.01052000   -2.95378900
 C                  0.13747600   -0.66464500   -4.30596900
 H                 -0.93655600   -0.70934300   -4.10446100
 H                  0.30619800   -0.20949800   -5.28749700
 H                  0.53778500   -1.68251800   -4.30332300
 C                  2.71512900    0.43452300   -3.53010000
 H                  3.16213700   -0.56367100   -3.52479800
 H                  2.78059900    0.85655100   -4.53415800
 H                  3.26711300    1.07055100   -2.82818900
 C                  0.21061400   -1.13655900    1.09961600
 C                 -1.04531200   -0.75976900    1.78884200
 H                 -1.36574200   -1.53522600    2.50167500
 C                  1.24758300   -1.62746100    1.99858300
 H                  2.21318000   -1.86526800    1.55111400
 H                  0.92271700   -2.39039600    2.73841800
 C                 -2.21259500   -0.36202000    0.91862800
 C                 -2.25800300    0.86684500    0.23918100
 C                 -3.26019100   -1.27133800    0.74867200
 C                 -3.33113600    1.16670700   -0.60436700
 H                 -1.45387200    1.58552900    0.36164600
 C                 -4.33003900   -0.97465200   -0.09658400
 H                 -3.24044200   -2.22135100    1.27711400
 C                 -4.36539700    0.24348900   -0.77918300
 H                 -3.35607100    2.12038800   -1.12026000
 H                 -5.13588500   -1.69296700   -0.22065700
 H                 -5.19825800    0.47820100   -1.43731000
 C                  1.50064800   -0.29777500    3.00043300
 C                  1.54310500    0.96843900    2.14236200
 N                  0.33621000   -0.03758800    3.76627800
 H                  2.41123400   -0.52134200    3.56300300
 O                  0.24411900    1.39703500    2.05649600
 O                  2.45967300    1.50871200    1.58586900
 C                 -0.10678600   -0.89841500    4.84826100
 H                 -0.39920100   -1.89984200    4.49850100
 H                  0.70477800   -1.00067600    5.56771700
 H                 -0.96270600   -0.43118100    5.34014200
 C                 -0.56301300    0.46242200    2.79339800
 H                 -1.44899400    0.95940600    3.18741500

-C -H -N -P -O 0
6-31G(d)
****
Au 0
SDD
****

Au
SDD



