%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

1 1
 P                  0.16676344   -0.05136955   -3.67777654
 Au                 0.55493173    0.17327170   -1.37035640
 C                 -1.42738801    0.67404337   -4.23362538
 H                 -1.43929551    1.74364812   -4.00521068
 H                 -1.55793501    0.53047625   -5.31133374
 H                 -2.25191610    0.19295323   -3.69976395
 C                  0.09990661   -1.79305919   -4.26042618
 H                 -0.69337867   -2.32434675   -3.72668675
 H                 -0.09864451   -1.82911642   -5.33661761
 H                  1.05426547   -2.28446878   -4.05045755
 C                  1.42706166    0.74152362   -4.75384659
 H                  2.40538428    0.29095217   -4.56341182
 H                  1.16545697    0.60982939   -5.80890939
 H                  1.48220591    1.80951819   -4.52428625
 C                  0.85747281    0.39103721    0.67590912
 C                  0.01169101   -0.55683408    1.49383745
 H                  0.24347250   -1.58887173    1.21730963
 C                  1.66072131    1.30711100    1.23653441
 H                  2.25627133    1.98154743    0.62772318
 H                  1.76160698    1.45415286    2.31127663
 C                 -1.48824577   -0.35310953    1.36255016
 C                 -2.02387173    0.93780751    1.27770218
 C                 -2.33987613   -1.46268157    1.32173171
 C                 -3.40152034    1.11531271    1.15151700
 H                 -1.35977844    1.79570571    1.30358564
 C                 -3.71833811   -1.28443934    1.18962495
 H                 -1.92643857   -2.46595097    1.38970422
 C                 -4.25019288    0.00494080    1.10416918
 H                 -3.81165901    2.11892925    1.08727582
 H                 -4.37367561   -2.14970430    1.15281661
 H                 -5.32240998    0.14455759    1.00038181
 C                  1.77627643   -0.24523540    4.62394511
 C                  0.68369487    0.67670031    4.86623623
 N                  1.52305693   -0.88713533    3.50859241
 H                  2.65570732   -0.42173292    5.22270566
 O                 -0.18002739    0.45214247    3.76291228
 O                  0.43275580    1.47673234    5.72243183
 C                  2.36323298   -1.89202038    2.83360473
 H                  2.64721750   -1.48596928    1.86093999
 H                  3.24132557   -2.05524790    3.45450321
 H                  1.78837226   -2.81262935    2.73094187
 C                  0.31662875   -0.57935414    3.00265797
 H                 -0.17395923   -1.48366129    3.29668519

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD



