%nprocshared=36
%mem=22GB
#p opt=(calcfc,maxstep=10) freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                  0.93484088   -0.76841805   -1.72085190
 C                  0.20751479   -1.85715978   -0.94833705
 C                  0.22125734   -0.50502107   -3.01729638
 H                  0.77256743   -0.04819411   -3.83531060
 C                  0.91957147   -2.64454757    0.07762646
 C                  2.11967580   -2.17354564    0.65212521
 C                  0.43822520   -3.89613861    0.52232625
 C                  2.78387642   -2.90149800    1.64211098
 H                  2.52894574   -1.22132318    0.33238677
 C                  1.09931761   -4.61834948    1.51149147
 H                 -0.44876507   -4.32214916    0.06477645
 C                  2.27828911   -4.12572310    2.08254248
 H                  3.70331177   -2.50731479    2.06767280
 H                  0.70433935   -5.58160205    1.82516543
 H                  2.79920839   -4.69694195    2.84598179
 N                 -1.82592376   -1.45898473   -2.20804780
 C                 -3.24661146   -1.19166407   -2.05823395
 H                 -3.44048327   -0.24875409   -1.52318562
 H                 -3.71857723   -1.13564957   -3.04425424
 H                 -3.71465112   -2.00097712   -1.49186164
 C                 -1.12318247   -2.05668774   -1.16986548
 H                 -1.72186712   -2.72200742   -0.55790393
 C                 -1.08302119   -0.77350968   -3.18680881
 H                 -1.62795068   -0.54504939   -4.09860601
 H                  1.97416043   -1.06268655   -1.90022872
 P                  0.27381247    2.90218287    0.77637475
 Au                 0.85086351    1.02827462   -0.55620411
 C                 -1.47791416    3.39762084    0.51793029
 H                 -2.10070655    2.52885636    0.74406267
 H                 -1.75306743    4.22872078    1.17708671
 H                 -1.64353043    3.68651708   -0.52349436
 C                  1.22851088    4.46256040    0.57217372
 H                  1.15370837    4.81030079   -0.46247080
 H                  0.83481762    5.23265811    1.24398822
 H                  2.28234722    4.28420216    0.80468209
 C                  0.32416631    2.57990948    2.58726921
 H                  1.33446435    2.29103135    2.88996926
 H                  0.01580933    3.47042370    3.14659456
 H                 -0.35940274    1.75574550    2.80790576
 H                 -1.28054257   -0.71490554    0.58624096
 O                 -1.71474644   -0.11543278    1.23978195
 C                 -2.82648013   -0.71526989    1.71718196
 O                 -3.19324927   -1.81911974    1.36209399
 C                 -3.53858082    0.16520528    2.71517397
 H                 -4.35744051   -0.38614219    3.17832708
 H                 -2.83779670    0.51568583    3.47822169
 H                 -3.93560481    1.04585073    2.20073398

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD



