%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

-1 1
 O                 -1.24923399   -0.31219123    0.00297626
 C                  0.01600750   -0.15887458   -0.01324522
 O                  0.84487710   -1.13110023    0.00317903
 C                  0.34370125    1.30856018    0.00246997
 H                 -0.02052629    1.77268729   -0.92055194
 H                 -0.16550947    1.79807579    0.83853833
 H                  1.42250236    1.44246024    0.08665680

C H O 0
6-31G(d)
****



