%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 O                 -0.99724057   -0.85201445   -0.00753286
 C                  0.16122927   -0.07970576   -0.01537399
 O                  1.26978642   -0.54516768    0.00295805
 C                 -0.20748653    1.37788303    0.00650108
 H                 -0.73725378    1.63316763   -0.91773999
 H                 -0.88671918    1.58090395    0.84038170
 H                  0.69484716    1.98300794    0.09840453
 H                 -0.97369743   -1.80868607    0.06878970

C H O 0
6-31G(d)
****



