%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 O                 -1.14685866    1.36562913    0.11955583
 C                  0.10738176    1.87654810   -0.00473474
 O                  1.07611471    1.21475292   -0.29176618
 C                  0.05251412    3.37224757    0.15794763
 H                 -0.58243416    3.80934619   -0.62020426
 H                 -0.39238930    3.62454467    1.12471769
 H                  1.05994377    3.78292378    0.08581695
 H                 -1.11211198    0.40243953    0.00961388
 O                  1.11205825   -1.30626894    0.07973731
 C                 -0.11543720   -1.88377325   -0.01695328
 O                 -1.11935341   -1.28068515   -0.31231816
 C                  0.01744175   -3.36945987    0.18718235
 H                  0.66688406   -3.79575626   -0.58497758
 H                  0.48340792   -3.57096331    1.15594915
 H                 -0.96824017   -3.83282457    0.13721634
 H                  1.09785014   -0.34050895   -0.01045439

C H O 0
6-31G(d)
****



