%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

0 1
 C                  0.08453721   -1.23555465   -0.02504077
 O                  1.31383909   -1.24581194   -0.07272208
 O                 -0.56924801    0.03612986   -0.04187508
 C                  0.08581582    1.22320890    0.01420272
 O                  1.31380447    1.19455845    0.08337527
 C                 -0.87740239    2.42427033   -0.02132355
 H                 -1.44397327    2.40037413   -0.92869691
 H                 -1.54207823    2.37329250    0.81563959
 H                 -0.31540437    3.33364777    0.02440284
 C                 -0.91437380   -2.40503470    0.05301816
 H                 -1.48394631   -2.32796112    0.95554063
 H                 -1.57354933   -2.36786952   -0.78900699
 H                 -0.37967398   -3.33183398    0.04675657

C H O 0
6-31G(d)
****



