%nprocshared=8
%mem=22GB
#p opt freq b3lyp gen nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

1 1
 C                  0.05404174   -1.23916411   -0.01890238
 O                  1.28388313   -1.24460623   -0.05087695
 O                 -0.60443550    0.02996925   -0.04356525
 C                  0.04521838    1.21956736    0.02136667
 O                  1.27232561    1.19567316    0.10621206
 C                 -0.92214968    2.41688032   -0.02596941
 H                 -1.47698452    2.39119409   -0.94051767
 H                 -1.59725980    2.36292494    0.80241163
 H                 -0.36433674    3.32842089    0.02730847
 C                 -0.94121102   -2.41256595    0.04590531
 H                 -1.52256385   -2.33813036    0.94110820
 H                 -1.58971553   -2.37758251   -0.80445817
 H                 -0.40286014   -3.33727039    0.04609459
 H                  1.92413808    0.21384817   -0.30050707

C H O 0
6-31G(d)
****



