%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

1 1
 P                 -0.50771146   -0.19947521   -3.68366920
 Au                -0.46378042    0.23500709   -1.37036711
 C                 -1.48372795    0.99986987   -4.67932146
 H                 -1.06879465    2.00233868   -4.54128635
 H                 -1.45835480    0.72833067   -5.73398378
 H                 -2.51990252    0.99816129   -4.32944551
 C                 -1.20763457   -1.84517913   -4.13352716
 H                 -2.23496511   -1.91194531   -3.76426972
 H                 -1.20243897   -1.97713777   -5.22049991
 H                 -0.61330957   -2.63033817   -3.66791358
 C                  1.16030357   -0.19285347   -4.46652345
 H                  1.78452858   -0.94641271   -4.00001608
 H                  1.07880921   -0.39263890   -5.53986943
 H                  1.62223038    0.78683954   -4.32193506
 C                 -0.37899870    0.48250885    0.67784283
 C                 -1.51277964    0.24457164    1.44527541
 H                 -2.44582223    0.17794295    0.86084970
 C                  0.87585217    0.82477498    1.30907327
 H                  1.63368312    1.30104309    0.62309175
 H                  0.91615395    1.16110292    2.35466089
 C                 -1.74183376    0.03788640    2.86697778
 C                 -0.73929920   -0.31831927    3.79509208
 C                 -3.07440209    0.10892241    3.33779317
 C                 -1.04068808   -0.54757859    5.12950424
 H                  0.28765953   -0.45111640    3.47297210
 C                 -3.37694306   -0.12670117    4.68117932
 H                 -3.87655477    0.35983099    2.64610283
 C                 -2.35976567   -0.45228887    5.57755252
 H                 -0.23631182   -0.82035813    5.81854105
 H                 -4.40401786   -0.06370030    5.02122749
 H                 -2.59406032   -0.64906712    6.62450708
 C                  1.85601382   -0.39076153    1.61616951
 C                  2.54126990    0.02169229    2.83988339
 N                  2.88657899   -0.39945421    0.62962460
 H                  1.16730160   -1.24119151    1.61017774
 O                  3.84298623    0.55022864    2.36452078
 O                  2.26300187    0.10642766    4.00436150
 C                  2.73875912   -0.95116663   -0.71458267
 H                  3.62158497   -0.70214071   -1.31051168
 H                  2.63393838   -2.04291316   -0.64712457
 H                  1.84618994   -0.51955745   -1.17100363
 N                  3.96086639    0.20430826    1.09671501

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD





