%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

1 1
 P                 -1.94493036   -0.08532120   -2.83029078
 Au                -0.69564298    0.02140802   -0.85150049
 C                 -3.43837810    0.98140631   -2.86083264
 H                 -3.14652213    2.02309984   -2.70100274
 H                 -3.94611562    0.88872681   -3.82660522
 H                 -4.12012760    0.67981584   -2.06071923
 C                 -2.55917499   -1.76666409   -3.23485100
 H                 -3.21694731   -2.11626676   -2.43420485
 H                 -3.11175262   -1.74967862   -4.17994784
 H                 -1.71203492   -2.45325181   -3.31952986
 C                 -0.97195666    0.42818841   -4.29960754
 H                 -0.09201607   -0.21390912   -4.39593465
 H                 -1.58228035    0.35033381   -5.20520946
 H                 -0.63953238    1.46240570   -4.17169301
 C                  0.56922627    0.05951984    0.85899897
 C                 -0.39103823    0.02479111    1.90891108
 H                 -0.89799304   -0.92032047    2.10201356
 C                  1.90775321   -0.00206457    0.84084363
 H                  2.42692992   -0.07002712    1.79893128
 H                 -1.04663884    0.88512414    2.03014182
 C                  2.79503879   -0.02427779   -0.33671992
 C                  3.98847416   -0.76575765   -0.27104088
 C                  2.51061267    0.67481218   -1.52458132
 C                  4.84057988   -0.85172405   -1.37213719
 H                  4.23755491   -1.29335614    0.64667170
 C                  3.36311790    0.59053393   -2.62584221
 H                  1.63126638    1.31108245   -1.57203392
 C                  4.52751327   -0.17979722   -2.55752246
 H                  5.75065060   -1.44134011   -1.30406565
 H                  3.12557808    1.14148756   -3.53195837
 H                  5.19336696   -0.24171508   -3.41360732
 C                 -0.62584987    0.63645419    5.34356039
 C                 -0.84125875   -0.78883118    5.31442115
 N                 -0.02545836    0.96594549    4.21522008
 H                 -0.88332226    1.35043285    6.10861654
 N                  0.26379206   -0.07593835    3.43674450
 O                 -0.28365230   -1.16716345    4.06269128
 O                 -1.33924507   -1.59063856    6.06106461
 C                  0.35264656    2.31075882    3.75700064
 H                 -0.32874418    2.59079962    2.95087335
 H                  0.25531106    2.99432675    4.59815280
 H                  1.38412635    2.27909071    3.40660777

C H P N O 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD





