%nprocshared=24
%mem=41GB
#p opt freq b3lyp genecp nosymm empiricaldispersion=gd3 scrf=(pcm,solvent=dichloromethane) scf=maxcyc=512

Opt freq

1 1
 P                 -0.87819342    0.13936178   -2.47904711
 Au                 0.45674185   -0.14307762   -0.58789589
 C                 -2.41415069    1.08230691   -2.14307955
 H                 -2.16047836    2.07181343   -1.75223627
 H                 -2.99597775    1.19464873   -3.06414187
 H                 -3.01569602    0.55541222   -1.39697170
 C                 -1.41571646   -1.44705244   -3.22532331
 H                 -2.00822712   -2.01495888   -2.50234609
 H                 -2.02116703   -1.25473710   -4.11751473
 H                 -0.53986599   -2.03990965   -3.50392157
 C                 -0.01911301    1.05073802   -3.81850218
 H                  0.88177903    0.50742317   -4.11750914
 H                 -0.68206006    1.15595400   -4.68395833
 H                  0.27109903    2.04370071   -3.46341663
 C                  2.09913947   -0.05859657    0.96493364
 C                  1.17210780   -0.81139474    1.62081194
 H                  1.23386984   -1.89545190    1.49690325
 C                  3.21410595    0.60323946    0.74830992
 H                  3.41431039    1.13906704   -0.17418713
 H                  3.99014702    0.61948590    1.51341123
 C                  0.15487940   -0.32572679    2.56317696
 C                  0.06726301    1.03165325    2.92840554
 C                 -0.73891946   -1.25540952    3.12427569
 C                 -0.89326588    1.44324222    3.84449239
 H                  0.75808616    1.75006220    2.49593277
 C                 -1.69879542   -0.83716132    4.04361310
 H                 -0.67089582   -2.30439040    2.84645242
 C                 -1.77816945    0.51065754    4.40262547
 H                 -0.95432573    2.48879860    4.13063913
 H                 -2.38048820   -1.56014501    4.48071634
 H                 -2.52600552    0.83695631    5.11919257

C H P 0
6-31G(d)
****
Au 0
SDD
****

Au 0
SDD







