%mem=15000MB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

0 1
 Pd                -1.01260400    0.19781000   -0.25605900
 C                 -1.26379500    2.07737000   -1.49351700
 C                 -0.28370500    2.77560600   -0.75047100
 C                 -2.51003100    1.69285400   -0.94606100
 H                 -1.07794700    1.89203800   -2.54593300
 O                  0.92956000   -2.54635200    0.23349300
 S                 -2.55272100   -1.79562400    0.13363500
 C                 -1.43566800   -3.09804700    0.87664400
 H                 -1.06191200   -2.71816900    1.83161500
 C                 -0.25175700   -3.28121200   -0.12443000
 H                 -0.57463600   -2.98477200   -1.12893000
 C                  0.08547700   -4.78682500   -0.11259500
 H                  0.38107500   -5.15074000   -1.10139000
 H                  0.93477500   -4.95289100    0.56258100
 C                 -2.01955200   -4.48811900    1.00802000
 C                 -1.16537200   -5.43497200    0.42407900
 C                 -3.18727300   -4.89786200    1.65715100
 C                 -1.48771900   -6.79146300    0.44769700
 C                 -3.50929700   -6.25803800    1.67933400
 H                 -3.84094900   -4.17778900    2.13661300
 C                 -2.66975500   -7.19863200    1.07235600
 H                 -0.82652000   -7.52340900   -0.00897300
 H                 -4.41939900   -6.58543100    2.17408500
 H                 -2.93380800   -8.25236200    1.09403900
 P                  1.03265900   -0.90797900    0.15034900
 O                  2.13625100   -0.60450800   -1.03256500
 O                  1.95188500   -0.82006200    1.53002400
 C                  3.29381700   -1.39509800   -1.12741100
 C                  3.02013200    0.06662200    1.70217300
 C                  4.23902800   -1.24065200   -0.09344400
 C                  3.46937200   -2.27006600   -2.20770400
 C                  4.13287600   -0.07703400    0.85045000
 C                  2.98281900    0.99210000    2.76337300
 C                  5.31489000   -2.14770100   -0.00771400
 C                  4.59449000   -3.10801600   -2.10916600
 C                  2.61666700   -2.36640200   -3.49947300
 C                  5.18082600    0.86996900    0.92541000
 C                  4.08265500    1.85590000    2.84516100
 C                  1.84320900    1.05916400    3.80484400
 C                  5.47823100   -3.10351200   -1.03259900
 C                  6.28071800   -2.14920600    1.15578600
 H                  4.78324700   -3.81976900   -2.90721200
 C                  2.07272200   -3.80567100   -3.66215100
 C                  1.41770400   -1.39887900   -3.58936700
 C                  3.54032900   -2.03759300   -4.70229600
 C                  5.14555200    1.84419900    1.94001700
 C                  6.32611100    0.88878000   -0.06213400
 H                  4.11480300    2.59218100    3.63888900
 C                  1.62545800   -0.32672200    4.46116700
 C                  2.16361300    2.04854600    4.94664900
 C                  0.53820200    1.54621200    3.13629900
 C                  6.61405600   -4.10041700   -0.99244900
 H                  7.29114500   -1.85102600    0.84703300
 H                  5.96379100   -1.47935800    1.95617300
 H                  6.36798500   -3.15829200    1.57588000
 H                  1.40474900   -4.06716200   -2.83447400
 H                  1.50210700   -3.88761700   -4.59500200
 H                  2.87251500   -4.55207400   -3.69503600
 H                  0.65649400   -1.59852500   -2.83067700
 H                  1.72219800   -0.35362700   -3.49181000
 H                  0.94663900   -1.52584900   -4.57175600
 H                  3.93073900   -1.01635300   -4.62523700
 H                  4.39329300   -2.71976200   -4.77137600
 H                  2.97465100   -2.11521000   -5.63858600
 C                  6.25084900    2.86667500    2.07883500
 H                  6.44611400    1.89444200   -0.48217200
 H                  7.28097700    0.63214000    0.41493500
 H                  6.16945400    0.19768300   -0.89068900
 H                  0.83825500   -0.25652300    5.22177500
 H                  1.33217500   -1.08544200    3.73407000
 H                  2.54219400   -0.66518400    4.95873100
 H                  2.26400700    3.07927400    4.58932500
 H                  1.34118700    2.03263100    5.67035200
 H                  3.08095800    1.77700500    5.48113500
 H                  0.66593300    2.55807700    2.73357200
 H                  0.22576900    0.89368200    2.31788200
 H                 -0.27392300    1.57890600    3.87289700
 H                  6.62144800   -4.72150700   -1.89317400
 H                  6.53536100   -4.77120100   -0.12688700
 H                  7.59045700   -3.60531700   -0.91799500
 H                  6.30484800    3.52901200    1.20467300
 H                  7.23658100    2.39433500    2.17485300
 H                  6.09223900    3.49484900    2.96039900
 C                 -3.97141900   -1.62609600    1.23871300
 C                 -5.21587500   -2.09218800    0.74791400
 C                 -3.86386800   -1.00712300    2.50509300
 C                 -6.34566800   -1.93669900    1.56158400
 C                 -5.02443800   -0.88235100    3.28060100
 C                 -6.25490400   -1.34142600    2.81758600
 H                 -7.30591100   -2.29412700    1.19990200
 H                 -4.95384000   -0.41305200    4.25813600
 H                 -7.14303200   -1.23228100    3.43384300
 C                 -5.37299500   -2.75790900   -0.60080200
 H                 -5.12153600   -2.07776600   -1.42123200
 H                 -4.72486900   -3.63546600   -0.69419300
 H                 -6.40818900   -3.08313900   -0.74038900
 C                 -2.56338500   -0.47617400    3.05206800
 H                 -1.86366100   -1.28022400    3.31130800
 H                 -2.05517900    0.16712200    2.32565000
 H                 -2.73969200    0.10595700    3.96109600
 C                 -1.04132100    5.30894100   -0.92578100
 H                 -0.24553200    5.50088000   -1.63312800
 C                 -0.70550500    5.65723000    0.42508400
 C                 -2.31701400    5.09734200   -1.54865700
 O                 -3.39761500    5.06688300   -0.70493400
 O                 -1.67571800    5.40411600    1.36494100
 O                 -2.46781600    4.93522900   -2.76456500
 O                  0.39725600    6.09648900    0.77301900
 C                 -4.67113900    4.97904900   -1.34996000
 H                 -5.40953800    5.02612200   -0.54678800
 H                 -4.81975500    5.81336500   -2.04279500
 H                 -4.77939900    4.04069500   -1.90013100
 C                 -1.33407200    5.76914700    2.70399300
 H                 -1.08673000    6.83282400    2.77510700
 H                 -2.21988800    5.55052000    3.30366800
 H                 -0.48198400    5.18874800    3.07241100
 C                  1.07269000    3.05999000   -1.21655600
 C                  2.00941800    3.59051000   -0.30712800
 C                  1.48556500    2.83529600   -2.54737800
 C                  3.30915800    3.88662200   -0.71146200
 H                  1.70353800    3.79293100    0.71303700
 C                  2.78447300    3.13197000   -2.94744400
 H                  0.78898800    2.43980700   -3.27913300
 C                  3.70296200    3.65851100   -2.03200600
 H                  4.01267200    4.30018300    0.00485100
 H                  3.08205100    2.95705700   -3.97756100
 H                  4.71566900    3.89147700   -2.34917600
 C                 -3.64527600    1.18715700   -1.73816500
 C                 -4.93806500    1.24387000   -1.18265700
 C                 -3.50490100    0.65910900   -3.03783000
 C                 -6.05068900    0.80382400   -1.89976100
 H                 -5.06690700    1.64633300   -0.18106300
 C                 -4.61599300    0.21827800   -3.75231900
 H                 -2.52154000    0.58659300   -3.49292000
 C                 -5.89545000    0.29010400   -3.18936300
 H                 -7.03804400    0.86356100   -1.45027600
 H                 -4.48439100   -0.18209000   -4.75384300
 H                 -6.76007800   -0.05147200   -3.75137500
 H                 -0.49401500    2.98203200    0.29214800
 H                 -2.78429800    2.13554300    0.01169800

C H P O S 0
6-31G*
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Pd 0
lanl2dz
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Pd 0
lanl2dz



