%nprocshared=12
%mem=15000MB
# freq rb3lyp/genecp scrf=check guess=tcheck geom=(connectivity,allcheck)
genchk

Title Card Required

0 1
 Pd                -0.76058100    0.09925400    0.50351800
 C                 -1.95155500   -1.56808000    1.49334900
 C                 -0.64291200   -1.99737500    1.12060500
 C                 -3.02594400   -1.55669400    0.58671600
 H                 -2.14901900   -1.33945900    2.53579400
 O                  1.62492200    2.26193000   -0.53706700
 S                 -1.78257000    2.44408300    0.31665200
 C                 -0.56246700    3.50021600   -0.61467500
 H                 -0.52902900    3.14844800   -1.64894300
 C                  0.83495100    3.31368300    0.04102500
 H                  0.70694400    3.13486400    1.11314800
 C                  1.56532000    4.65334100   -0.17212100
 H                  2.27816900    4.86934500    0.62913500
 H                  2.13328600    4.60067100   -1.11059400
 C                 -0.78058800    4.99960400   -0.53640300
 C                  0.43637100    5.64748000   -0.27419000
 C                 -1.94555200    5.74386100   -0.73452600
 C                  0.49694400    7.03708000   -0.18288400
 C                 -1.88338200    7.13789100   -0.64108000
 H                 -2.88962000    5.25809200   -0.95430700
 C                 -0.67265100    7.78115200   -0.36324100
 H                  1.44013000    7.53561100    0.02554900
 H                 -2.78620800    7.72463700   -0.78586800
 H                 -0.64022800    8.86471000   -0.29005400
 P                  1.37566600    0.66962000   -0.22015900
 O                  2.57561600    0.22195700    0.82469200
 O                  1.96414600    0.21751600   -1.70343700
 C                  3.91852600    0.55974400    0.56735200
 C                  2.61030600   -1.01087900   -1.89582800
 C                  4.51238200   -0.02533100   -0.56295400
 C                  4.61597000    1.40027300    1.45400500
 C                  3.84503800   -1.18341900   -1.24555400
 C                  2.06749100   -1.96839400   -2.77389900
 C                  5.77829800    0.43467900   -0.98892200
 C                  5.88774400    1.79383000    1.01278900
 C                  4.12165000    1.75395600    2.87719800
 C                  4.47513700   -2.44732200   -1.28392100
 C                  2.76017900   -3.18616200   -2.82609700
 C                  0.84072300   -1.71369500   -3.67863300
 C                  6.45275400    1.38265000   -0.19731300
 C                  6.41558500   -0.04043100   -2.27518600
 H                  6.47426300    2.46303800    1.63064900
 C                  5.14508500    2.62578700    3.63587300
 C                  2.78376000    2.52316200    2.88004100
 C                  3.94972400    0.43519700    3.67032800
 C                  3.90684200   -3.46146700   -2.07745000
 C                  5.72471800   -2.75005700   -0.48758900
 H                  2.38855400   -3.97341300   -3.47056700
 C                  1.04347000   -0.41242700   -4.49441900
 C                  0.63441100   -2.85446200   -4.69901800
 C                 -0.44879500   -1.61599700   -2.83547300
 C                  7.80016400    1.92695200   -0.61434600
 H                  7.32868400   -0.62002500   -2.08614900
 H                  5.74095600   -0.66222000   -2.86503200
 H                  6.71162700    0.81552400   -2.89351300
 H                  5.30779400    3.59243200    3.14529800
 H                  4.76428000    2.82629100    4.64332300
 H                  6.11371900    2.12626000    3.74466600
 H                  2.86365500    3.45095600    2.30340100
 H                  1.97014900    1.92033900    2.47480200
 H                  2.51602400    2.79280400    3.90868500
 H                  3.20300600   -0.21794600    3.21280800
 H                  4.89776500   -0.11255300    3.72545200
 H                  3.62634400    0.65430500    4.69561000
 C                  4.53734600   -4.83321200   -2.15894000
 H                  5.60348100   -3.68530100    0.07134400
 H                  6.59882100   -2.88527500   -1.13841100
 H                  5.95933100   -1.96116500    0.22804500
 H                  0.18578300   -0.25592700   -5.15992400
 H                  1.14177900    0.46464000   -3.85246700
 H                  1.94287900   -0.48384800   -5.11762100
 H                  0.40360200   -3.80978100   -4.21508600
 H                 -0.21371400   -2.60296100   -5.34532800
 H                  1.51134900   -2.99503500   -5.34097500
 H                 -0.64962700   -2.56013900   -2.31589200
 H                 -0.38678300   -0.82319300   -2.08592300
 H                 -1.30725600   -1.40224400   -3.48452900
 H                  8.20166900    2.60348700    0.14600100
 H                  7.73711800    2.48600700   -1.55718200
 H                  8.53403700    1.12665400   -0.77294000
 H                  4.52421200   -5.34455900   -1.18752900
 H                  5.58741500   -4.78251600   -2.47320900
 H                  4.00305900   -5.46661700   -2.87318100
 C                 -3.36333500    2.66990300   -0.53317300
 C                 -4.41875600    3.20795700    0.24447100
 C                 -3.55532400    2.31512600   -1.88722100
 C                 -5.65784800    3.41244900   -0.37354600
 C                 -4.81502000    2.54807800   -2.45817300
 C                 -5.85616100    3.09657800   -1.71618600
 H                 -6.47366800    3.82867000    0.21100900
 H                 -4.97218500    2.28517100   -3.50101600
 H                 -6.82394200    3.26815500   -2.17911900
 C                 -4.25861400    3.57341400    1.70342300
 H                 -4.00692800    2.69999700    2.31576800
 H                 -3.46154100    4.31013800    1.85078700
 H                 -5.19041100    3.99546300    2.09089000
 C                 -2.47704700    1.71458100   -2.75583600
 H                 -1.86508400    2.49051600   -3.23423800
 H                 -1.80609100    1.06602300   -2.18705800
 H                 -2.92349300    1.12246900   -3.56038500
 C                 -3.86756900   -4.12020300    0.49341200
 H                 -4.78666300   -3.89260300    1.01668200
 C                 -2.79181300   -4.64300700    1.27977800
 C                 -3.99776600   -4.16937400   -0.93176700
 O                 -3.13333200   -4.61949800    2.62297800
 O                 -2.85553800   -4.50937900   -1.61658800
 O                 -5.03525500   -3.89346000   -1.54775300
 O                 -1.68308400   -5.04678200    0.92755700
 C                 -3.00946700   -4.61243400   -3.03368300
 H                 -2.03366500   -4.91949900   -3.41453800
 H                 -3.76577300   -5.35863100   -3.29693700
 H                 -3.29750700   -3.65361500   -3.47587000
 C                 -2.14837000   -5.14121600    3.51548800
 H                 -1.23670800   -4.53590800    3.50535400
 H                 -2.60296000   -5.11035800    4.50828800
 H                 -1.88622100   -6.17283700    3.25895500
 H                 -0.55621800   -2.50927800    0.16530000
 H                 -2.81172900   -1.81811400   -0.44343400
 C                 -4.35888200   -1.02278800    0.85320200
 C                 -5.28127600   -0.93666900   -0.21048300
 C                 -4.76957700   -0.59270600    2.13324200
 C                 -6.56690800   -0.44383900   -0.00152100
 H                 -4.99113200   -1.29182700   -1.19351900
 C                 -6.05497200   -0.10037900    2.33749700
 H                 -4.08820700   -0.65217600    2.97582600
 C                 -6.95905100   -0.02314600    1.27178200
 H                 -7.26412600   -0.39022900   -0.83255700
 H                 -6.35568800    0.22115800    3.33068400
 H                 -7.96214400    0.36052900    1.43557000
 C                  0.40146400   -2.36424500    2.09644000
 C                  1.44898700   -3.20651000    1.67859400
 C                  0.38039900   -1.94882000    3.44232500
 C                  2.43276500   -3.62777600    2.57089000
 H                  1.48007300   -3.53889700    0.64432500
 C                  1.36227200   -2.37426800    4.33572800
 H                 -0.40456500   -1.28740600    3.79744000
 C                  2.39230600   -3.21713800    3.90615000
 H                  3.22756500   -4.28325400    2.22544500
 H                  1.32382500   -2.04590000    5.37089800
 H                  3.15496100   -3.54852800    4.60530300

 1 25 1.0
 2 3 1.5 4 1.5 5 1.0
 3 117 1.0 130 1.0
 4 118 1.0 119 1.0
 5
 6 10 1.0 25 1.0
 7 8 1.0 84 1.0
 8 9 1.0 10 1.0 15 1.0
 9
 10 11 1.0 12 1.0
 11
 12 13 1.0 14 1.0 16 1.0
 13
 14
 15 16 1.5 17 1.5
 16 18 1.5
 17 19 1.5 20 1.0
 18 21 1.5 22 1.0
 19 21 1.5 23 1.0
 20
 21 24 1.0
 22
 23
 24
 25 26 1.0 27 1.0
 26 28 1.0
 27 29 1.0
 28 30 1.5 31 1.5
 29 32 1.5 33 1.5
 30 32 1.0 34 1.5
 31 35 1.5 36 1.0
 32 37 1.5
 33 38 1.5 39 1.0
 34 40 1.5 41 1.0
 35 40 1.5 42 1.0
 36 43 1.0 44 1.0 45 1.0
 37 46 1.5 47 1.0
 38 46 1.5 48 1.0
 39 49 1.0 50 1.0 51 1.0
 40 52 1.0
 41 53 1.0 54 1.0 55 1.0
 42
 43 56 1.0 57 1.0 58 1.0
 44 59 1.0 60 1.0 61 1.0
 45 62 1.0 63 1.0 64 1.0
 46 65 1.0
 47 66 1.0 67 1.0 68 1.0
 48
 49 69 1.0 70 1.0 71 1.0
 50 72 1.0 73 1.0 74 1.0
 51 75 1.0 76 1.0 77 1.0
 52 78 1.0 79 1.0 80 1.0
 53
 54
 55
 56
 57
 58
 59
 60
 61
 62
 63
 64
 65 81 1.0 82 1.0 83 1.0
 66
 67
 68
 69
 70
 71
 72
 73
 74
 75
 76
 77
 78
 79
 80
 81
 82
 83
 84 85 1.5 86 1.5
 85 87 1.5 93 1.0
 86 88 1.5 97 1.0
 87 89 1.5 90 1.0
 88 89 1.5 91 1.0
 89 92 1.0
 90
 91
 92
 93 94 1.0 95 1.0 96 1.0
 94
 95
 96
 97 98 1.0 99 1.0 100 1.0
 98
 99
 100
 101 102 1.0 103 1.5 104 1.5
 102
 103 105 1.0 108 2.0
 104 106 1.0 107 2.0
 105 113 1.0
 106 109 1.0
 107
 108
 109 110 1.0 111 1.0 112 1.0
 110
 111
 112
 113 114 1.0 115 1.0 116 1.0
 114
 115
 116
 117
 118
 119 120 1.5 121 1.5
 120 122 1.5 123 1.0
 121 124 1.5 125 1.0
 122 126 1.5 127 1.0
 123
 124 126 1.5 128 1.0
 125
 126 129 1.0
 127
 128
 129
 130 131 1.5 132 1.5
 131 133 1.5 134 1.0
 132 135 1.5 136 1.0
 133 137 1.5 138 1.0
 134
 135 137 1.5 139 1.0
 136
 137 140 1.0
 138
 139
 140

