%nprocshared=12
%mem=15000MB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

0 1
 Pd                -1.03271200    0.15516900   -0.06071200
 C                 -1.32828100    2.38180600    0.00106400
 C                 -2.56339800    1.74174000   -0.24215300
 C                 -0.54039100    2.98021100   -1.06733700
 O                  1.08474400   -2.47931700   -0.11036500
 S                 -2.36003900   -1.97985000   -0.58312600
 C                 -1.24154000   -3.42382600   -0.22155000
 H                 -1.08934500   -3.47602600    0.85990300
 C                  0.11961100   -3.15568900   -0.92551500
 H                 -0.06195600   -2.58517800   -1.84183000
 C                  0.66821200   -4.54821700   -1.29306800
 H                  1.28398800   -4.52602700   -2.19754000
 H                  1.30594900   -4.90350100   -0.47262200
 C                 -1.66845400   -4.76117800   -0.79503200
 C                 -0.57753600   -5.38935100   -1.41546100
 C                 -2.90754600   -5.40167600   -0.73151200
 C                 -0.72085800   -6.64737800   -1.99903400
 C                 -3.04989500   -6.66320500   -1.31821000
 H                 -3.75299300   -4.93321300   -0.23972600
 C                 -1.96629400   -7.28081900   -1.95193000
 H                  0.12378500   -7.12992100   -2.48426500
 H                 -4.01236100   -7.16597600   -1.28103600
 H                 -2.09214600   -8.25928700   -2.40739500
 P                  1.05070600   -0.85657600    0.19141200
 O                  2.27719100   -0.23475600   -0.74346800
 O                  1.79007500   -1.07864600    1.66893200
 C                  3.51441200   -0.89753300   -0.81462800
 C                  2.71825800   -0.18065300    2.19833100
 C                  4.27794400   -0.94401200    0.36367700
 C                  3.95645700   -1.44020600   -2.03583600
 C                  3.93704400   -0.03718300    1.51032900
 C                  2.45401600    0.46427300    3.42249800
 C                  5.41365100   -1.78263500    0.41429500
 C                  5.11581200   -2.22433000   -1.94815400
 C                  3.33422800   -1.08952500   -3.40935900
 C                  4.85884600    0.94660600    1.93424000
 C                  3.42750000    1.38294800    3.83763400
 C                  1.21584200    0.17016300    4.29805000
 C                  5.81127500   -2.45241500   -0.75755500
 C                  6.19585000   -1.99895200    1.69035900
 H                  5.50031000   -2.69630400   -2.84433500
 C                  1.85098200   -1.49987700   -3.53169400
 C                  3.45553700    0.44078400   -3.61403200
 C                  4.08655100   -1.77565100   -4.56987600
 C                  4.58526300    1.66848100    3.11076400
 C                  6.11483000    1.26672200    1.15439400
 H                  3.28020900    1.92118500    4.76627700
 C                  1.11092300   -1.34832500    4.58473500
 C                  1.29836000    0.88062900    5.66688200
 C                 -0.06956800    0.67039100    3.60408100
 C                  7.00656800   -3.37844100   -0.75805900
 H                  7.20606000   -1.57351600    1.62594700
 H                  5.70137300   -1.55535400    2.55558000
 H                  6.32006500   -3.07080000    1.88564500
 H                  1.22020600   -0.96779700   -2.81808000
 H                  1.48681800   -1.26159700   -4.53848300
 H                  1.72948200   -2.57831500   -3.38313400
 H                  2.92242400    0.99429800   -2.83741100
 H                  4.50638000    0.75287700   -3.59594600
 H                  3.03484900    0.72455300   -4.58702400
 H                  5.14192400   -1.48524800   -4.60827700
 H                  4.03111400   -2.86882000   -4.50860500
 H                  3.62851900   -1.47462100   -5.51846000
 C                  5.53919900    2.72730900    3.61586300
 H                  6.18427500    2.34591500    0.97302800
 H                  7.02071500    0.98231900    1.70588200
 H                  6.14038300    0.76399900    0.18708200
 H                  0.24808500   -1.54406700    5.23325500
 H                  0.99114700   -1.93097400    3.66986100
 H                  2.00814400   -1.70558000    5.10439600
 H                  1.30219600    1.97195600    5.56934400
 H                  0.41878200    0.60944600    6.26144900
 H                  2.18724600    0.58139700    6.23379600
 H                 -0.02594000    1.75583700    3.45220900
 H                 -0.22400300    0.20192000    2.62902100
 H                 -0.94437400    0.45109100    4.22900100
 H                  7.20326000   -3.76283500   -1.76344800
 H                  6.85178500   -4.24099400   -0.09647500
 H                  7.91624600   -2.87428300   -0.40770200
 H                  5.63097300    3.56318400    2.90964500
 H                  6.55165300    2.33057400    3.76376800
 H                  5.19735000    3.13700600    4.57118500
 H                 -1.11226800    2.71641400    1.01089900
 C                 -3.88359900   -2.30918400    0.33070600
 C                 -5.06517100   -2.44211800   -0.44013900
 C                 -3.91509200   -2.39357100    1.74098000
 C                 -6.26854000   -2.69548600    0.22865900
 C                 -5.14610000   -2.65410400    2.36011000
 C                 -6.31203200   -2.81038200    1.61697600
 H                 -7.17992800   -2.80539100   -0.35296900
 H                 -5.18069300   -2.72593300    3.44416500
 H                 -7.25512600   -3.01094300    2.11789600
 C                 -5.07620200   -2.32947500   -1.94866800
 H                 -4.73583400   -1.34427500   -2.28766800
 H                 -4.41746900   -3.07099000   -2.41367700
 H                 -6.08929900   -2.48396500   -2.33137900
 C                 -2.69422200   -2.22760500    2.61322900
 H                 -2.16036000   -3.17767700    2.74779400
 H                 -1.98742100   -1.50647000    2.19307100
 H                 -2.98428600   -1.88177300    3.60983000
 C                  0.86176700    3.40509400   -0.85972300
 C                  1.72414600    3.49968500   -1.96703100
 C                  1.36604500    3.75587000    0.40714700
 C                  3.04368100    3.92569700   -1.81575200
 H                  1.35561200    3.23550100   -2.95363000
 C                  2.68350800    4.18224600    0.55806100
 H                  0.72791600    3.70320800    1.28313100
 C                  3.52835300    4.27141500   -0.55291700
 H                  3.69141400    3.98855100   -2.68563800
 H                  3.05170500    4.44499000    1.54567700
 H                  4.55482700    4.60726400   -0.43403300
 C                 -3.65386800    1.61221200    0.74751600
 C                 -3.46172600    1.75306200    2.13684000
 C                 -4.96411300    1.37757600    0.28791600
 C                 -4.53473500    1.66598300    3.02184800
 H                 -2.46592800    1.92918700    2.53130700
 C                 -6.03852000    1.29356400    1.17362400
 H                 -5.13875800    1.27840900   -0.78059600
 C                 -5.83049400    1.43670900    2.54748400
 H                 -4.35850800    1.77975900    4.08850200
 H                 -7.03926300    1.11724900    0.78827900
 H                 -6.66533400    1.37239500    3.23978800
 H                 -0.75274500    2.58996500   -2.05907700
 H                 -2.89293500    1.68759000   -1.27892200
 C                 -1.43503900    4.93340700   -1.54129000
 H                 -0.82254900    5.56605600   -0.90969200
 C                 -2.83423300    4.83624900   -1.10591500
 C                 -1.07815200    5.07170900   -2.96014200
 O                 -3.78764300    4.39743200   -1.73015200
 O                 -0.12790600    5.73526300   -3.35677900
 O                 -2.95197000    5.29864900    0.17050900
 O                 -1.84640400    4.33632800   -3.80066600
 C                 -4.28165900    5.29384800    0.71394000
 H                 -4.18599100    5.70076600    1.72131500
 H                 -4.94273700    5.92536800    0.11333500
 H                 -4.68550400    4.27986100    0.74948600
 C                 -1.51313100    4.44277100   -5.19341400
 H                 -2.23804400    3.81734200   -5.71515600
 H                 -1.59132100    5.47911300   -5.53296500
 H                 -0.49734700    4.08302500   -5.37953600

C H P O S 0
6-31G*
****
Pd 0
lanl2dz
****

Pd 0
lanl2dz


