%nprocshared=12
%mem=15000MB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

0 1
 Pd                -0.57298500   -0.11772700   -0.69434900
 C                 -1.89188600   -1.92258100   -0.99215700
 C                 -2.84628400   -2.05233300    0.09767500
 C                 -0.53325400   -2.28812800   -0.83426100
 H                 -2.30477000   -1.87978400   -1.99578000
 O                  1.38769700    2.00205700    1.03480000
 S                 -1.46414100    2.25545900   -1.14456900
 C                 -0.38180100    3.37005200   -0.08527900
 H                  0.47195000    3.53408200   -0.75373000
 C                  0.13687900    2.69067500    1.21579800
 H                 -0.60749000    1.98166400    1.58140700
 C                  0.33903600    3.83489800    2.23142700
 H                  0.09904000    3.52851500    3.25475800
 H                  1.39456200    4.13586300    2.22070000
 C                 -0.94199300    4.69158900    0.38284300
 C                 -0.54101600    4.94367400    1.70435300
 C                 -1.68351600    5.63900800   -0.32498600
 C                 -0.90660000    6.13078800    2.33853900
 C                 -2.04739100    6.82871400    0.31213000
 H                 -1.98217500    5.45884000   -1.35243300
 C                 -1.66825000    7.07027700    1.63736000
 H                 -0.59938400    6.32594300    3.36281200
 H                 -2.63172400    7.56930500   -0.22665700
 H                 -1.96302600    7.99661900    2.12277100
 P                  1.47629600    0.62847100    0.12739800
 O                  2.15526000   -0.49356400    1.14041500
 O                  2.80766400    1.18619700   -0.71240600
 C                  3.30245300   -0.19162400    1.89164900
 C                  3.77833400    0.31782800   -1.21545200
 C                  4.49906900    0.00546200    1.18145900
 C                  3.22142200   -0.15216900    3.29490900
 C                  4.57902900   -0.35568400   -0.27383300
 C                  3.98173400    0.21945700   -2.60484300
 C                  5.63167800    0.49093700    1.87426800
 C                  4.38633300    0.28052000    3.94329100
 C                  1.99421600   -0.65007700    4.09515900
 C                  5.49256300   -1.33587500   -0.72338200
 C                  4.94615300   -0.71689800   -3.00150000
 C                  3.26069500    1.11325800   -3.63968000
 C                  5.55557200    0.64657200    3.27110300
 C                  6.90847100    0.87540700    1.16089000
 H                  4.39187900    0.35405600    5.02420000
 C                  0.72530200    0.18744500    3.81649100
 C                  1.72417700   -2.13035600    3.72654900
 C                  2.24790600   -0.59307000    5.61702900
 C                  5.66333500   -1.51685000   -2.10868300
 C                  6.27436000   -2.20866700    0.23335600
 H                  5.14654100   -0.85080800   -4.05769700
 C                  3.49021500    2.60578200   -3.29387100
 C                  3.80739500    0.89012100   -5.06656400
 C                  1.74674800    0.80614900   -3.68286200
 C                  6.73320700    1.17270200    4.06031900
 H                  7.73922500    0.20843300    1.42616300
 H                  6.79641800    0.85514700    0.07615300
 H                  7.21680400    1.88763400    1.44882700
 H                  0.38124300    0.07567900    2.78738700
 H                 -0.08512900   -0.14408600    4.47745000
 H                  0.90522900    1.25045800    4.01087200
 H                  1.49437600   -2.24576700    2.66436300
 H                  2.59388000   -2.75540800    3.96046200
 H                  0.87236500   -2.50949000    4.30505800
 H                  3.11234100   -1.19643600    5.91493000
 H                  2.40399200    0.43222000    5.97163800
 H                  1.37155600   -0.99196500    6.13969200
 C                  6.63170800   -2.54658900   -2.64604000
 H                  6.17776700   -3.26428300   -0.04660500
 H                  7.34747400   -1.97677800    0.21296900
 H                  5.92975700   -2.10282800    1.26287700
 H                  2.99921100    3.24007400   -4.04224100
 H                  3.08921000    2.86265900   -2.31149700
 H                  4.56041000    2.84542200   -3.30126000
 H                  3.63197800   -0.13134700   -5.42192600
 H                  3.29208400    1.56917800   -5.75505400
 H                  4.88069600    1.10113600   -5.13499400
 H                  1.56897400   -0.23647300   -3.96790300
 H                  1.26036300    0.97628200   -2.72037700
 H                  1.25785200    1.44939700   -4.42596100
 H                  6.51826900    1.16799600    5.13314600
 H                  6.98436700    2.20322100    3.77642400
 H                  7.63771500    0.57330300    3.89649200
 H                  6.33186000   -3.56764200   -2.37488500
 H                  7.64522700   -2.40243500   -2.25091700
 H                  6.68786300   -2.49787300   -3.73770800
 C                  0.34168700   -2.75975500   -1.93158300
 C                 -0.01991400   -2.70283800   -3.29187400
 C                  1.58500900   -3.33489100   -1.60589200
 C                  0.82722100   -3.20259400   -4.28037800
 H                 -0.97141100   -2.26977400   -3.58561300
 C                  2.43176200   -3.83482100   -2.59326100
 H                  1.88327700   -3.38884300   -0.56179900
 C                  2.05761900   -3.77190400   -3.93828500
 H                  0.52171600   -3.15215600   -5.32232900
 H                  3.38330500   -4.27753400   -2.31162100
 H                  2.71344100   -4.16514200   -4.71015000
 C                 -4.19395800   -1.45139700    0.04746100
 C                 -4.85466400   -1.15717600   -1.15964700
 C                 -4.86496300   -1.18737800    1.25680300
 C                 -6.13669300   -0.61040200   -1.15434700
 H                 -4.37194900   -1.36203800   -2.10959300
 C                 -6.14751000   -0.64193600    1.26204800
 H                 -4.37350100   -1.42323400    2.19683300
 C                 -6.78897900   -0.35151700    0.05422100
 H                 -6.62924400   -0.38894000   -2.09695800
 H                 -6.64561500   -0.44293300    2.20706200
 H                 -7.78887400    0.07341300    0.05467400
 H                 -2.41045200   -2.04998600    1.09337200
 H                 -0.22527700   -2.63350100    0.15027600
 C                 -3.18097400    2.80799900   -1.01586800
 C                 -3.92073200    2.74193600    0.18530700
 C                 -3.78015900    3.25067800   -2.22190600
 C                 -5.25772700    3.16257800    0.16588600
 C                 -5.12273100    3.64768500   -2.18927900
 C                 -5.85668800    3.61473000   -1.00588600
 H                 -5.83254200    3.12126800    1.08707900
 H                 -5.59132700    3.99144400   -3.10762100
 H                 -6.89562300    3.93294100   -0.99977600
 C                 -3.33976300    2.24637400    1.48524200
 H                 -4.13754900    1.99291500    2.18868600
 H                 -2.72301700    1.35463300    1.33341400
 H                 -2.71345200    3.01115000    1.95960100
 C                 -3.03767000    3.31136000   -3.53917200
 H                 -2.70405600    2.32008600   -3.86665900
 H                 -3.68656400    3.72137700   -4.31859600
 H                 -2.14196100    3.93919100   -3.47575500
 C                 -3.24094500   -4.21599800    0.15055400
 H                 -2.87435300   -4.45070500   -0.84183700
 C                 -2.28055000   -4.62777200    1.18371900
 C                 -4.69990800   -4.37029200    0.21714900
 O                 -5.40224700   -4.42644900   -0.78566000
 O                 -1.16297200   -5.06146400    0.92525600
 O                 -5.22131500   -4.40080800    1.46552100
 O                 -2.68772000   -4.40804000    2.45757200
 C                 -6.65182300   -4.50122900    1.53153400
 H                 -6.89100600   -4.55276200    2.59439800
 H                 -7.11942700   -3.62262900    1.07946300
 H                 -7.00304100   -5.40082100    1.01926300
 C                 -1.74770100   -4.77755100    3.47792300
 H                 -1.50904800   -5.84292800    3.41914800
 H                 -0.82372600   -4.20058000    3.38321300
 H                 -2.24078800   -4.55185700    4.42404800

C H P O S 0
6-31G*
****
Pd 0
lanl2dz
****

Pd 0
lanl2dz




