%nprocshared=12
%mem=15000MB
#p opt freq b3lyp/genecp
scrf=(solvent=dichloromethane,pcm)

Title Card Required

1 1
 Pd                 0.96611800   -1.07703400   -0.82529800
 C                  1.54294000   -2.30184200   -2.57770100
 C                  0.12734300   -2.25819900   -2.44064800
 C                  2.30949600   -3.32148400   -1.93987400
 H                  2.05486100   -1.59234400   -3.22328400
 O                 -0.20288900    1.70484500    0.62111100
 S                  2.75134700   -0.28343200    0.79127100
 C                  2.16129700    1.39538100    1.39459900
 H                  1.61783900    1.10488900    2.30276600
 C                  1.16648200    2.12145000    0.44509500
 H                  1.45890700    1.95407900   -0.59254100
 C                  1.29732800    3.61615600    0.79557800
 H                  1.11421000    4.26239500   -0.06827600
 H                  0.55243900    3.87019200    1.56126500
 C                  3.19334100    2.45352800    1.70912500
 C                  2.69782400    3.71808000    1.35225700
 C                  4.43888200    2.32859600    2.32580500
 C                  3.45672600    4.86450000    1.58199700
 C                  5.19768300    3.47993900    2.55603900
 H                  4.82200900    1.35782200    2.62199800
 C                  4.71380200    4.73808600    2.18096300
 H                  3.07569700    5.84343600    1.30303800
 H                  6.17231900    3.39425900    3.02795100
 H                  5.31713000    5.62357500    2.36052600
 H                 -0.41765700   -1.57484600   -3.08780200
 C                 -0.65730300   -3.46105400   -1.92255700
 H                 -1.16791200   -3.20456800   -0.98749300
 H                 -1.45321800   -3.69487100   -2.64157800
 C                  1.59587800   -4.36859200   -1.11555000
 H                  2.22122700   -5.26182200   -1.02229100
 H                  1.47801800   -3.97241600   -0.09727100
 C                  0.22368400   -4.70822200   -1.71645000
 H                 -0.29240800   -5.43037300   -1.07525900
 H                  0.37544600   -5.20454900   -2.68344700
 H                  3.34203100   -3.10138900   -1.69144500
 C                  4.43929100   -0.16967900    0.14667600
 C                  4.77605700    0.54287400   -1.02636900
 C                  5.40567100   -0.94168100    0.83949900
 C                  6.10080100    0.48253000   -1.48064000
 C                  6.71360700   -0.97162800    0.33892700
 C                  7.06406300   -0.26387800   -0.80789300
 H                  6.37128900    1.03129800   -2.37870900
 H                  7.46282300   -1.55816100    0.86349700
 H                  8.08468200   -0.29704300   -1.17869500
 C                  5.09084800   -1.73805200    2.08761100
 H                  6.00123700   -2.20372600    2.47558100
 H                  4.66621200   -1.11090800    2.87912900
 H                  4.36309200   -2.53435300    1.89351400
 C                  3.78631700    1.37010600   -1.80648400
 H                  2.83851600    0.83809200   -1.94942600
 H                  3.56487800    2.31240400   -1.29160700
 H                  4.18973100    1.62482400   -2.79082400
 P                 -0.72737900    0.26496200    0.02904500
 O                 -1.85957900    0.63172700   -1.10461600
 O                 -1.65489200   -0.05756200    1.37025700
 C                 -2.96672800    1.44910800   -0.81554800
 C                 -2.72290300   -0.95933800    1.25148300
 C                 -3.92946500    0.89735100    0.05473600
 C                 -3.10187300    2.71081600   -1.41139800
 C                 -3.82380600   -0.53842900    0.48139500
 C                 -2.69266100   -2.18572900    1.94097600
 C                 -4.99921100    1.70082700    0.49918900
 C                 -4.21704000    3.44997700   -0.97793400
 C                 -2.21445600    3.35173400   -2.50955900
 C                 -4.85099700   -1.46268700    0.18897600
 C                 -3.76447500   -3.04748800    1.66595100
 C                 -1.61759900   -2.55478800    2.98976600
 C                 -5.13170600    3.00223300   -0.02882800
 C                 -5.99124400    1.22879500    1.53832800
 H                 -4.37409900    4.44082700   -1.39272900
 C                 -1.65273900    4.69897800   -1.99352600
 C                 -1.02008500    2.50259900   -2.98994700
 C                 -3.10208500    3.61435700   -3.75418000
 C                 -4.80076100   -2.73939900    0.78086300
 C                 -5.98810700   -1.12916900   -0.75026600
 H                 -3.79802500   -4.01480700    2.15248000
 C                 -1.51928000   -1.43543000    4.05636400
 C                 -1.97187600   -3.86008100    3.73500200
 C                 -0.23989600   -2.77052600    2.32617000
 C                 -6.26079700    3.90827000    0.40657700
 H                 -6.98877600    1.07555600    1.10599300
 H                 -5.68455000    0.29424000    2.00957300
 H                 -6.10503400    1.98161300    2.32692700
 H                 -1.03338400    4.54761400   -1.10268800
 H                 -1.03108300    5.16637200   -2.76674100
 H                 -2.44506700    5.40752100   -1.73254100
 H                 -0.28658800    2.33650200   -2.19821100
 H                 -1.33285700    1.52863800   -3.37502600
 H                 -0.51581300    3.04230700   -3.80068700
 H                 -3.50161000    2.67497200   -4.15354300
 H                 -3.94789600    4.27205100   -3.53207700
 H                 -2.50709700    4.09218700   -4.54174400
 C                 -5.87319300   -3.76807500    0.50251900
 H                 -6.09892900   -1.91134600   -1.51061500
 H                 -6.94797200   -1.06944900   -0.22084600
 H                 -5.83085200   -0.18047800   -1.26529600
 H                 -0.77866300   -1.71246800    4.81637300
 H                 -1.22079700   -0.48014800    3.62039100
 H                 -2.48256700   -1.29698700    4.56117400
 H                 -1.99285000   -4.72835200    3.06683600
 H                 -1.20854000   -4.05258100    4.49691400
 H                 -2.93951100   -3.79261500    4.24442400
 H                 -0.28534200   -3.59263800    1.60211700
 H                  0.11271000   -1.87901900    1.80318200
 H                  0.50617700   -3.03297100    3.08671200
 H                 -6.24457200    4.84874500   -0.15209700
 H                 -6.19479500    4.15460600    1.47435700
 H                 -7.24172400    3.44201100    0.25147000
 H                 -5.88849900   -4.06267400   -0.55503500
 H                 -6.87519300   -3.38715000    0.73636800
 H                 -5.71144000   -4.67243400    1.09654500

C H P O S 0
6-31G*
****
Pd 0
lanl2dz
****

Pd 0
lanl2dz



