%nprocshared=12
%mem=15000MB
#p opt freq b3lyp/genecp
scrf=(solvent=dichloromethane,pcm) 

Title Card Required

1 1
 Pd                -0.91714300   -1.10602900    0.68000000
 C                 -1.13673200   -3.14036000    1.55005300
 C                 -1.96035200   -2.87860500    2.68356500
 C                  0.22876400   -2.74067000    1.52971700
 H                 -1.54672700   -3.73169500    0.73472000
 O                  0.09491900    1.78070000   -0.79573100
 S                 -2.93661300    0.38091200    0.37077300
 C                 -2.42860400    1.60627100   -0.94681700
 H                 -2.17784400    1.04825000   -1.85261600
 C                 -1.16820000    2.35784100   -0.41717900
 H                 -1.22647500    2.42295700    0.67385800
 C                 -1.25618400    3.77483300   -1.01533400
 H                 -0.80730000    4.52663100   -0.35929700
 H                 -0.70345400    3.79405600   -1.96393100
 C                 -3.40684700    2.73026500   -1.22229800
 C                 -2.73470100    3.96179300   -1.24493300
 C                 -4.77641700    2.66888500   -1.48836400
 C                 -3.42708200    5.14322400   -1.50575700
 C                 -5.46958200    3.85520000   -1.74836800
 H                 -5.30364400    1.72128600   -1.49308900
 C                 -4.80185900    5.08458900   -1.75228000
 H                 -2.90577600    6.09686300   -1.51843500
 H                 -6.53664100    3.81912500   -1.94897100
 H                 -5.35386500    5.99876300   -1.95219100
 H                  0.85690900   -3.14298400    0.73896700
 C                 -1.37924900   -2.11538300    3.85186800
 H                 -1.48208700   -1.04286600    3.63187500
 H                 -1.97163100   -2.29944000    4.75351900
 C                  0.95243400   -2.30978100    2.80237300
 H                  1.86675700   -2.90928700    2.90253700
 H                  1.28947500   -1.27203700    2.70313900
 C                  0.09729000   -2.47549300    4.07393400
 H                  0.15499000   -3.51707100    4.41404700
 H                  0.50802000   -1.86420600    4.88412800
 H                 -3.03381100   -2.83222100    2.53478000
 P                  0.64417200    0.35119000   -0.20684600
 O                  1.80679100    0.69822700    0.92002800
 O                  1.53697100    0.06517300   -1.56807100
 C                  2.98172300    1.41182200    0.61633200
 C                  2.51796200   -0.93294800   -1.49073100
 C                  3.86656300    0.82880400   -0.30893900
 C                  3.26091500    2.61317600    1.29284000
 C                  3.66870000   -0.59262500   -0.75055100
 C                  2.36150700   -2.16455700   -2.14321300
 C                  4.97334500    1.57851100   -0.76639000
 C                  4.39714500    3.29788800    0.83921700
 C                  2.47703100    3.10630800    2.53221000
 C                  4.63194300   -1.58291900   -0.47356600
 C                  3.36313500   -3.11068200   -1.85912300
 C                  1.25364000   -2.56598700   -3.14939500
 C                  5.21911000    2.84015000   -0.19352500
 C                  5.88539100    1.07490400   -1.86241200
 H                  4.66031600    4.24244900    1.29965500
 C                  0.98734000    3.36767100    2.22359900
 C                  2.58844500    2.03549500    3.64649400
 C                  3.06155200    4.42034800    3.09281700
 C                  4.45321700   -2.86949400   -1.02575900
 C                  5.82932300   -1.32303700    0.41208200
 H                  3.28438800   -4.09735400   -2.30455300
 C                  0.33355000   -1.41328500   -3.60133500
 C                  1.92789500   -3.11311300   -4.43533400
 C                  0.37386800   -3.67687100   -2.52877800
 C                  6.38147400    3.69166600   -0.65145200
 H                  6.88220700    0.82396700   -1.47650400
 H                  5.48577500    0.18774900   -2.35591200
 H                  6.03032500    1.84802700   -2.62575400
 H                  0.46195700    2.44180600    1.99000700
 H                  0.50028800    3.81635500    3.09763400
 H                  0.87387600    4.05937700    1.38157500
 H                  2.15904200    1.08068400    3.33090900
 H                  3.63612800    1.86741400    3.92151500
 H                  2.05343900    2.37048300    4.54370500
 H                  4.10878900    4.31204400    3.39474300
 H                  2.99271100    5.24250600    2.37134900
 H                  2.49195400    4.71260300    3.98172100
 C                  5.44429500   -3.97779700   -0.75206400
 H                  5.89811600   -2.08403000    1.19861800
 H                  6.76858800   -1.37339200   -0.15411700
 H                  5.78132000   -0.34605400    0.89429800
 H                 -0.33073600   -1.78574900   -4.39030800
 H                 -0.29153300   -1.03847200   -2.79044400
 H                  0.90240000   -0.57200300   -4.00881700
 H                  2.53995500   -4.00043100   -4.25036400
 H                  1.15713200   -3.39262600   -5.16310200
 H                  2.56756500   -2.35110800   -4.89511700
 H                  0.96563400   -4.55307800   -2.24205400
 H                 -0.14271600   -3.30802200   -1.63525800
 H                 -0.38561100   -4.00533400   -3.24898500
 H                  6.46348300    4.59835900   -0.04479300
 H                  6.26952100    4.00159900   -1.69876400
 H                  7.33527200    3.15377900   -0.58340400
 H                  5.48661000   -4.23101000    0.31521300
 H                  6.46266800   -3.69659700   -1.04823100
 H                  5.17579700   -4.88657400   -1.29880600
 C                 -4.44510600   -0.44692400   -0.18486300
 C                 -5.58898500   -0.27259000    0.63263200
 C                 -4.47418800   -1.28450600   -1.32295400
 C                 -6.76251600   -0.95095800    0.28004000
 C                 -5.67707300   -1.93300800   -1.63502800
 C                 -6.81196000   -1.77123600   -0.84499700
 H                 -7.64768400   -0.82469900    0.89747100
 H                 -5.71352100   -2.57550000   -2.51075500
 H                 -7.73310700   -2.28589100   -1.10360600
 C                 -5.59782900    0.61738700    1.85610500
 H                 -4.88533200    0.28010300    2.61736600
 H                 -5.32786700    1.64849800    1.60379300
 H                 -6.59341900    0.62617000    2.30870300
 C                 -3.28075100   -1.49833100   -2.21915200
 H                 -3.14236200   -0.65922200   -2.91268200
 H                 -2.35491200   -1.60181400   -1.64278100
 H                 -3.41178900   -2.39864100   -2.82637500

C H P O S 0
6-31G*
****
Pd 0
lanl2dz
****

Pd 0
lanl2dz



