%mem=15000MB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

1 1
 Pd                 0.95316300   -1.35878200    0.57167900
 C                  0.55798200   -3.49045700    1.02656800
 C                 -0.62034100   -3.34789100    1.82734700
 C                  1.82788700   -3.13357400    1.53393000
 H                  0.46593100   -3.95414700    0.04780900
 P                 -0.61271500    0.22936300   -0.13709900
 O                  0.04958500    1.70303700   -0.43991100
 O                 -1.56621500    0.20178000   -1.50475100
 O                 -1.68490700    0.56046500    1.06305900
 C                 -2.73563300   -0.56729900   -1.51461400
 C                 -2.71268000    1.51276200    0.91533600
 C                 -3.78511500   -0.11573100   -0.69193400
 C                 -2.85042600   -1.68127900   -2.36679200
 C                 -3.70446500    1.23705000   -0.04242100
 C                 -2.74320900    2.63569000    1.76122600
 C                 -4.93584500   -0.92212400   -0.54183000
 C                 -4.03740300   -2.41484600   -2.22777600
 C                 -1.79756500   -2.05876800   -3.43456600
 C                 -4.65823700    2.23653900   -0.34282600
 C                 -3.74430000    3.57048900    1.46241800
 C                 -1.83133100    2.81023400    2.99965600
 C                 -5.04678600   -2.09245100   -1.31714300
 H                 -4.18970300   -3.28980200   -2.84822600
 C                 -0.49554700   -2.56405700   -2.77390600
 C                 -2.30375700   -3.18524100   -4.36180400
 C                 -1.49340100   -0.83543900   -4.33491800
 C                 -4.65676000    3.42263800    0.41475500
 H                 -3.81906300    4.47056600    2.06047700
 C                 -2.19452800    4.08112000    3.79742400
 C                 -0.33843700    2.92602700    2.61788400
 C                 -2.02954800    1.60101200    3.94778100
 H                 -0.04320800   -1.81547100   -2.11960100
 H                 -0.68929500   -3.46115600   -2.17350200
 H                  0.23798600   -2.82869400   -3.54592500
 H                 -2.47369600   -4.12409300   -3.82291000
 H                 -3.23163000   -2.90858000   -4.87455500
 H                 -1.54633000   -3.38178000   -5.12849300
 H                 -2.40243900   -0.49494200   -4.84450100
 H                 -1.08740700    0.00211000   -3.76494900
 H                 -0.76243100   -1.11456800   -5.10333600
 C                 -5.64919300    4.52794000    0.13321200
 H                 -1.55394900    4.13920200    4.68415000
 H                 -2.03247900    4.99489900    3.21467400
 H                 -3.23448700    4.07042300    4.14163700
 H                  0.25409400    3.14149300    3.51558200
 H                  0.03966000    2.00378400    2.17803400
 H                 -0.17605300    3.73864800    1.90104200
 H                 -3.07305900    1.53124100    4.27669900
 H                 -1.75851200    0.65914400    3.46411400
 H                 -1.40259400    1.71970100    4.84002700
 C                 -6.25949100   -2.98892600   -1.20505300
 C                 -6.04015800   -0.57771400    0.43203300
 H                 -6.96606200   -0.29671400   -0.08654600
 H                 -6.28381100   -1.44487400    1.05719400
 H                 -5.76498400    0.24575700    1.09239000
 C                 -5.65814800    2.08392600   -1.46710600
 H                 -5.45077000    1.21206100   -2.08893600
 H                 -6.68482600    1.99167000   -1.08921300
 H                 -5.64199600    2.96913500   -2.11369000
 H                 -5.50075300    4.96177200   -0.86438500
 H                 -6.68480800    4.16737900    0.16775200
 H                 -5.55066800    5.33630000    0.86381500
 H                 -7.19137700   -2.44148700   -1.39400300
 H                 -6.20339500   -3.81228700   -1.92322200
 H                 -6.35150100   -3.42702600   -0.20250800
 S                  2.96159500    0.16013800    0.72611600
 C                  2.51063800    1.81022800   -0.04977400
 H                  2.16137000    2.35712400    0.83448400
 C                  1.34389400    1.75531400   -1.06955600
 H                  1.46847100    0.88556700   -1.71771300
 C                  1.48968700    3.04022300   -1.90441500
 H                  1.09324300    2.92615900   -2.91803100
 H                  0.92730000    3.84887200   -1.41832700
 C                  3.56965000    2.60580100   -0.77809600
 C                  2.97679300    3.30485600   -1.84393200
 C                  4.92378100    2.77212800   -0.48762300
 C                  3.74161500    4.15197500   -2.64369000
 C                  5.68861600    3.62217800   -1.29249400
 H                  5.38532000    2.25008800    0.34347300
 C                  5.10409600    4.30208700   -2.36628200
 H                  3.28566500    4.69100500   -3.47004900
 H                  6.74619800    3.75241400   -1.08142700
 H                  5.71185100    4.95496200   -2.98658200
 H                 -1.57126200   -3.23836900    1.31858700
 C                 -0.49846400   -2.79087600    3.22749200
 H                 -0.55566100   -1.69620200    3.15595700
 H                 -1.35724800   -3.10279900    3.82996400
 C                  2.04747600   -2.85118100    3.01704200
 H                  2.91987500   -3.42224900    3.35954600
 H                  2.30454900   -1.79498600    3.16802600
 C                  0.82573100   -3.21245500    3.88145200
 H                  0.91419900   -2.74760300    4.86878200
 H                  0.81145400   -4.29682600    4.04910400
 H                  2.70391700   -3.41837700    0.95529800
 C                  4.50019200   -0.47358100    0.01318500
 C                  4.60285300   -0.93544900   -1.31817800
 C                  5.59097100   -0.57806400    0.91298100
 C                  5.82329500   -1.48334700   -1.73683700
 C                  6.78619900   -1.13749700    0.44334900
 C                  6.90735800   -1.58400900   -0.86996100
 H                  5.91393000   -1.83733100   -2.76015600
 H                  7.62999000   -1.21939200    1.12283400
 H                  7.84336300   -2.01375700   -1.21559900
 C                  5.52519600   -0.11980000    2.35401500
 H                  6.50184100   -0.23941700    2.83162100
 H                  5.23265400    0.93244400    2.43861400
 H                  4.79597500   -0.69688300    2.93364600
 C                  3.47174700   -0.86152700   -2.31198600
 H                  2.52644300   -1.20332500   -1.87541100
 H                  3.32352400    0.16446300   -2.66917000
 H                  3.68885600   -1.48121900   -3.18675600
 N                 -1.17747900   -5.31578900    2.30376300
 H                 -2.05217100   -5.35435400    2.82663500
 H                 -1.30181600   -5.82313300    1.42875500
 H                 -0.45321800   -5.78672700    2.84345400

C H P N O S 0
6-31G*
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Pd 0
lanl2dz
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Pd 0
lanl2dz

