%mem=15000MB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

1 1
 Pd                -0.94654300   -1.47493800   -0.00709400
 C                 -0.33459600   -3.56330800   -0.31757900
 C                  0.51007200   -3.36705100   -1.45751800
 C                 -1.74209600   -3.49243600   -0.43965000
 H                  0.12635600   -3.83561600    0.62798900
 P                  0.58181000    0.28288400    0.17227100
 O                 -0.11775900    1.76551300    0.29701700
 O                  1.64620600    0.49247000    1.43927600
 O                  1.52394000    0.45771900   -1.16013400
 C                  2.77837100   -0.33232600    1.48076000
 C                  2.60175400    1.36304200   -1.23255600
 C                  3.74968800   -0.09427100    0.49013800
 C                  2.93511800   -1.29013000    2.49938100
 C                  3.67305800    1.15193900   -0.34615800
 C                  2.60009700    2.36531400   -2.21938100
 C                  4.83125500   -0.99287600    0.35884400
 C                  4.05588400   -2.12229100    2.35960400
 C                  2.01007700   -1.39260300    3.73495000
 C                  4.70430700    2.11688800   -0.27978200
 C                  3.67452600    3.26313200   -2.14890400
 C                  1.56257500    2.45338800   -3.36398400
 C                  4.96555700   -2.02972900    1.30260500
 H                  4.23459400   -2.89200900    3.10095900
 C                  0.60963300   -1.91997200    3.35034300
 C                  2.58349000   -2.35879600    4.79485500
 C                  1.88229300   -0.00428300    4.41073300
 C                  4.68564100    3.19163600   -1.18803000
 H                  3.73069000    4.07165500   -2.86736900
 C                  1.93490700    3.55021300   -4.38559800
 C                  0.15003000    2.78656800   -2.83392500
 C                  1.52709100    1.10905400   -4.13352700
 H                  0.10344500   -1.27448700    2.62859700
 H                  0.67897800   -2.92297500    2.91269000
 H                 -0.02278000   -1.98731400    4.24459200
 H                  2.63647800   -3.39147300    4.43233200
 H                  3.58307000   -2.05737700    5.12724300
 H                  1.92658700   -2.35502900    5.67154000
 H                  2.86574300    0.36522200    4.72420900
 H                  1.43554500    0.73630800    3.74466000
 H                  1.25316500   -0.08495500    5.30530800
 C                  5.76127200    4.25363000   -1.15932300
 H                  1.20086900    3.54118500   -5.19881000
 H                  1.91925200    4.55212200   -3.94232400
 H                  2.92278700    3.38387000   -4.82934800
 H                 -0.54335400    2.89157100   -3.67769400
 H                 -0.23263000    2.01057900   -2.17224800
 H                  0.15252000    3.73201100   -2.27918300
 H                  2.51150300    0.87756400   -4.55740800
 H                  1.22744400    0.27942500   -3.48914400
 H                  0.81135000    1.17466500   -4.96201500
 C                  6.10572400   -3.01867100    1.21281700
 C                  5.83642700   -0.88301800   -0.76570000
 H                  6.83153200   -0.60604300   -0.39394100
 H                  5.95146500   -1.84819000   -1.27333000
 H                  5.54059500   -0.14432200   -1.51189600
 C                  5.80959800    2.04821100    0.75045800
 H                  5.62853400    1.27980500    1.50289900
 H                  6.78412700    1.84308500    0.28822300
 H                  5.90648900    3.00931500    1.26892200
 H                  5.75058000    4.81643400   -0.21675900
 H                  6.76525000    3.82163700   -1.25555200
 H                  5.62519500    4.97054900   -1.97443500
 H                  7.08188300   -2.51761400    1.22017400
 H                  6.08319100   -3.71944800    2.05267800
 H                  6.06312500   -3.60660300    0.28654000
 S                 -2.97952700   -0.17835400    0.68178000
 C                 -2.60390200    1.64253100    0.55922000
 H                 -2.56115100    1.90993100   -0.49916400
 C                 -1.22120000    1.92959100    1.20600800
 H                 -1.08576600    1.27951400    2.07913800
 C                 -1.30355400    3.39004600    1.68569200
 H                 -0.65188200    3.57934900    2.54384300
 H                 -0.97970300    4.05160300    0.87084700
 C                 -3.52843300    2.56343500    1.32982200
 C                 -2.77657900    3.55892200    1.97392800
 C                 -4.92062100    2.55697200    1.41879800
 C                 -3.40941800    4.54547300    2.72814700
 C                 -5.55353400    3.54728300    2.17712300
 H                 -5.50943500    1.79957800    0.91126500
 C                 -4.80414000    4.53226900    2.82961600
 H                 -2.82819800    5.31287500    3.23275400
 H                 -6.63672000    3.54912700    2.26004300
 H                 -5.30904000    5.29257600    3.41903000
 H                  1.51664700   -3.00359900   -1.28692100
 C                 -0.12212900   -3.08792800   -2.80162500
 H                 -0.27175600   -2.00225400   -2.87519800
 H                  0.57189800   -3.35557800   -3.60452000
 C                 -2.43393700   -3.52903000   -1.79531100
 H                 -3.21350800   -4.30168700   -1.77158200
 H                 -2.96329700   -2.58544600   -1.97657600
 C                 -1.46134300   -3.82452500   -2.95234600
 H                 -1.92251100   -3.56056200   -3.90959400
 H                 -1.26761000   -4.90418600   -2.98813300
 H                 -2.33800900   -3.79505500    0.41868800
 N                  1.34869700   -5.25204900   -1.84929300
 H                  2.08048400   -5.19967800   -2.55754600
 H                  1.76174900   -5.59315100   -0.98237400
 H                  0.64789300   -5.92593300   -2.15406200
 C                 -4.41782400   -0.45811600   -0.37761800
 C                 -5.55214000   -1.02765500    0.25306300
 C                 -4.40226900   -0.19862100   -1.76774600
 C                 -6.67971900   -1.29787600   -0.53129300
 C                 -5.56259800   -0.48219400   -2.50359900
 C                 -6.69266800   -1.02086700   -1.89705100
 H                 -7.55734800   -1.72953500   -0.05797900
 H                 -5.56507000   -0.28012300   -3.57148100
 H                 -7.57891300   -1.23423500   -2.48791800
 C                 -5.59075300   -1.35682900    1.72955400
 H                 -4.83158600   -2.09888700    2.00321500
 H                 -5.40707700   -0.47181000    2.34828300
 H                 -6.56898300   -1.76453900    1.99960200
 C                 -3.21221900    0.36817600   -2.50587000
 H                 -3.21188900    1.46561300   -2.49442100
 H                 -2.26344800    0.03130600   -2.07552300
 H                 -3.23969200    0.06362400   -3.55654900

C H P N O S 0
6-31G*
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Pd 0
lanl2dz
****

Pd 0
lanl2dz

