%nproc=12
%mem=22200MB
#p opt=(modredun,ts,calcfc,noeigentest) freq b97d scrf=(solvent=benzene,SMD) gen
pseudo=read scfcyc=300

TS3_insertion  Energy= -939.494458133

+1 1
 Au                -0.00377700    0.64899300   -0.15257700
 C                  0.31510300    2.74463800   -0.43821800
 C                 -0.68730000    3.52640500    0.36307000
 O                 -1.93309600    3.39035100   -0.14680300
 O                 -0.43247500    4.18353400    1.37428900
 C                 -3.00074400    4.00777700    0.61849500
 H                 -2.88598000    5.10176400    0.61708500
 H                 -3.92400300    3.71545200    0.10543000
 H                 -2.99395800    3.63571000    1.65212400
 C                 -0.36185700   -1.33084600    0.09088800
 C                 -1.44429100   -3.31254500    0.29553600
 C                 -0.10333100   -3.56285500    0.39977700
 H                 -2.30466500   -3.96961400    0.33751700
 H                  0.44993900   -4.48247800    0.54867000
 N                 -1.57748700   -1.94140300    0.10185300
 N                  0.53898600   -2.33319000    0.27909800
 C                  1.79105000    3.25743000   -0.04081100
 C                  2.34590300    4.05143700   -1.14333900
 C                  2.66245900    2.19027900    0.48002900
 C                  3.56697000    3.74818100   -1.71915200
 H                  1.73278700    4.86818400   -1.52862700
 C                  3.88702900    1.90099200   -0.09627200
 H                  1.52117600    3.92996000    0.82145700
 C                  4.32243800    2.66713400   -1.20175200
 H                  3.94760800    4.32028500   -2.56524300
 H                  4.49741900    1.08033100    0.27717200
 H                  5.27810100    2.42247300   -1.67077800
 H                  2.30390700    1.62795600    1.34222600
 H                  0.14522800    2.90777100   -1.51409500
 C                  1.96170400   -2.09833000    0.31304800
 C                  2.60403300   -2.06887800    1.57269400
 C                  2.62903600   -1.85942800   -0.90724100
 C                  3.99271700   -1.84358600    1.57772300
 C                  4.01964800   -1.64625300   -0.84602400
 C                  4.69668200   -1.64975300    0.37938000
 H                  4.52933500   -1.82366400    2.52610400
 H                  4.56943800   -1.48240500   -1.77392900
 H                  5.77777200   -1.49666200    0.40552500
 C                 -2.80296100   -1.19157200   -0.04878300
 C                 -3.42951200   -1.18458400   -1.31521100
 C                 -3.25546900   -0.43101400    1.05050900
 C                 -4.58975000   -0.40167700   -1.44974500
 C                 -4.42192200    0.33376300    0.86146700
 C                 -5.08426100    0.34612600   -0.37144800
 H                 -5.10549300   -0.37069300   -2.40919000
 H                 -4.80749200    0.92351200    1.69402500
 H                 -5.98958200    0.94356500   -0.49735800
 C                 -2.55062900   -0.42335300    2.40362000
 H                 -1.60191500   -0.96884900    2.31426900
 C                 -2.81680800   -1.91371800   -2.50964600
 H                 -2.24398000   -2.77621400   -2.13679700
 C                  1.91410300   -1.83353400   -2.25452300
 H                  0.83357400   -1.92117000   -2.08525700
 C                  1.80558200   -2.17242600    2.87112600
 H                  0.92109800   -2.80070200    2.68816900
 C                  1.29203800   -0.76627500    3.26995000
 H                  0.68154700   -0.82980500    4.18563100
 H                  2.14287700   -0.09401700    3.47309400
 H                  0.67863300   -0.32222300    2.47183300
 C                  2.59018600   -2.80909100    4.03423500
 H                  1.91451900   -2.96703200    4.88939500
 H                  3.02093400   -3.78151200    3.74705500
 H                  3.40886300   -2.15618700    4.37732400
 C                  2.14807600   -0.49446700   -2.98560200
 H                  3.21363500   -0.35412700   -3.23112100
 H                  1.57739000   -0.47621000   -3.92779200
 H                  1.82077000    0.35421800   -2.36503400
 C                  2.35258200   -3.02671100   -3.13128800
 H                  2.14037500   -3.98576400   -2.63173000
 H                  1.81318000   -3.00901400   -4.09250500
 H                  3.43327100   -2.98433500   -3.34335100
 C                 -2.20553700    1.00995200    2.85750200
 H                 -1.66137100    0.98033400    3.81528000
 H                 -1.57386400    1.51921500    2.11589000
 H                 -3.11664400    1.61074900    3.00814600
 C                 -3.40941100   -1.14326100    3.46684400
 H                 -4.36965500   -0.62215600    3.61253100
 H                 -3.62723800   -2.18143100    3.16779000
 H                 -2.87918600   -1.16324000    4.43335100
 C                 -1.81930200   -0.97495700   -3.23278000
 H                 -1.03020000   -0.62408900   -2.55091600
 H                 -1.34603200   -1.50174900   -4.07828900
 H                 -2.34643500   -0.08999400   -3.62585800
 C                 -3.86270700   -2.45497200   -3.50380700
 H                 -3.35919600   -3.06183400   -4.27305700
 H                 -4.61230800   -3.08520600   -2.99898300
 H                 -4.39099500   -1.63867200   -4.02162500

B 17 23 F

-Si -C -N -O -H
6-31g(d)
*****
-Au 0
lanl2dz
F  1  1.0
1.050    1.0000
*****

-Au 0
lanl2dz







