%nprocshared=12
%mem=15000MB
#p opt freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

0 1
 Pd                -0.79819400    0.01408700    0.25933500
 C                 -1.84748200   -1.60499900    1.46058800
 C                 -0.44466600   -1.84618200    1.33909800
 C                 -2.73860100   -1.93514800    0.42633800
 H                 -2.24436800   -1.22647200    2.39693000
 O                  1.37740700    2.36717100   -0.75910900
 S                 -2.11090800    1.82642400   -0.98554100
 C                 -0.90309600    3.23281900   -1.30343500
 H                 -0.55048300    2.98009900   -2.31131500
 C                  0.32157100    3.25752500   -0.35009000
 H                  0.00054100    2.99589200    0.65924300
 C                  0.82494000    4.71231300   -0.37836300
 H                  1.28925400    5.01062100    0.56658100
 H                  1.58388400    4.81370900   -1.16561700
 C                 -1.40983900    4.65738000   -1.26355100
 C                 -0.41953800    5.49490900   -0.72418200
 C                 -2.60842200    5.19442700   -1.73493000
 C                 -0.63311700    6.86854100   -0.62182400
 C                 -2.82059800    6.57234000   -1.63146700
 H                 -3.37195200    4.56050400   -2.17132100
 C                 -1.84373300    7.40324300   -1.07234700
 H                  0.13203100    7.51565500   -0.20090700
 H                 -3.75420300    6.99891300   -1.98711000
 H                 -2.02478000    8.47157600   -0.99282000
 C                 -3.57995100    2.47230700   -0.14896600
 C                 -3.57147200    2.89276200    1.20001100
 C                 -4.78033400    2.44438400   -0.90222100
 C                 -4.78119500    3.31184500    1.77076300
 C                 -5.96084400    2.87408800   -0.28313600
 C                 -5.96522600    3.30929500    1.03950400
 H                 -4.78513500    3.64009600    2.80669800
 H                 -6.88621500    2.86265200   -0.85236500
 H                 -6.89152500    3.63892800    1.50184000
 C                 -4.85005300    1.96328800   -2.33536900
 H                 -5.85403600    2.12657000   -2.73744600
 H                 -4.13516000    2.48051800   -2.98404000
 H                 -4.63029600    0.89236000   -2.40942700
 C                 -2.32901700    2.92011600    2.05446600
 H                 -1.72503100    2.01428700    1.92108000
 H                 -1.69605400    3.78140300    1.80898100
 H                 -2.59362200    3.00409600    3.11257500
 P                  1.30265200    0.76797100   -0.39123300
 O                  2.49473400    0.50872000    0.70598400
 O                  2.00616100    0.30531100   -1.82101400
 C                  3.82709800    0.88128500    0.45860500
 C                  2.66135700   -0.93449100   -1.89244600
 C                  4.49456800    0.15581000   -0.55014100
 C                  4.44607900    1.88281700    1.22049400
 C                  3.85370900   -1.05991200   -1.15455700
 C                  2.16266000   -1.95454300   -2.72385200
 C                  5.78256400    0.56105100   -0.95501900
 C                  5.75599600    2.20244400    0.82041700
 C                  3.89920400    2.60495200    2.47896500
 C                  4.46998400   -2.32678100   -1.05370900
 C                  2.84566500   -3.17635500   -2.63729400
 C                  0.98951800   -1.76927300   -3.71391100
 C                  6.41369000    1.60914200   -0.25356900
 C                  6.49996400   -0.06852800   -2.12820200
 H                  6.29178700    2.96988300    1.37024700
 C                  4.00794300    4.13810200    2.29037900
 C                  2.43757100    2.29128500    2.85571700
 C                  4.77643800    2.17807400    3.68484200
 C                  3.93925500   -3.39794200   -1.79743700
 C                  5.66470000   -2.57339000   -0.15975200
 H                  2.50473900   -4.01095700   -3.23755800
 C                  1.22630600   -0.51998700   -4.59828700
 C                  0.85414900   -2.97614300   -4.66894600
 C                 -0.34966500   -1.63822200   -2.95540900
 C                  7.79846600    2.07986000   -0.63601800
 H                  7.38072000   -0.63983200   -1.80673100
 H                  5.85504300   -0.73957400   -2.69667200
 H                  6.86363900    0.70739400   -2.81210800
 H                  3.42704400    4.46798600    1.42206500
 H                  3.61606600    4.65038400    3.17719900
 H                  5.03970900    4.47317400    2.14805000
 H                  1.73645800    2.60823900    2.08018200
 H                  2.27491100    1.22980100    3.05022900
 H                  2.19081400    2.84539100    3.76959100
 H                  4.69619900    1.09904500    3.85986000
 H                  5.83324800    2.41840000    3.53087500
 H                  4.44275700    2.69542200    4.59268200
 C                  4.55740300   -4.77579400   -1.72751700
 H                  5.48048000   -3.43509300    0.49287700
 H                  6.56578200   -2.80931000   -0.74080600
 H                  5.89041900   -1.71463100    0.47361600
 H                  0.40441000   -0.41602700   -5.31713400
 H                  1.28235200    0.39696900   -4.00925000
 H                  2.15833900   -0.61935900   -5.16762500
 H                  0.59050700   -3.89809400   -4.13971700
 H                  0.05208800   -2.77149200   -5.38696200
 H                  1.77306400   -3.15390700   -5.23915900
 H                 -0.55396700   -2.54467300   -2.37347500
 H                 -0.35143700   -0.78588200   -2.27031500
 H                 -1.17253600   -1.49769900   -3.66850700
 H                  8.15464800    2.84905700    0.05573300
 H                  7.81740200    2.50768200   -1.64694400
 H                  8.52596200    1.25856600   -0.62893900
 H                  4.48666600   -5.20104800   -0.71794800
 H                  5.62338000   -4.75959400   -1.98782200
 H                  4.05464700   -5.46479700   -2.41245100
 C                 -3.04567956   -4.30810436    0.61283437
 H                 -4.12543156   -4.24026436    0.62700137
 C                 -2.43103756   -4.54059936   -0.65654863
 C                 -2.44567256   -4.42345136    1.90792337
 O                 -1.23666756   -4.61754236   -0.95815663
 O                 -3.05649956   -4.27664136    2.97300837
 O                 -3.40270256   -4.62169836   -1.64722363
 O                 -1.10279156   -4.70619236    1.90979037
 C                 -2.91510056   -4.84384836   -2.96975763
 H                 -3.80154156   -4.93503936   -3.60137763
 H                 -2.29666556   -4.00973736   -3.31752963
 H                 -2.32181756   -5.76218936   -3.02710463
 C                 -0.52470056   -4.88487736    3.20476937
 H                  0.53124844   -5.09711836    3.02867337
 H                 -0.62467556   -3.98302736    3.81486437
 H                 -0.99339156   -5.72152836    3.73334437
 H                 -2.31057300   -2.30784300   -0.49653500
 H                 -0.14449200   -2.52037300    0.53929300
 C                  0.50044600   -1.78837300    2.47070600
 C                  1.75260000   -2.41779300    2.33763500
 C                  0.20430100   -1.15257600    3.69257500
 C                  2.67467000   -2.41470400    3.38251300
 H                  1.99918300   -2.91166900    1.40135700
 C                  1.12496100   -1.15326300    4.73926100
 H                 -0.74930200   -0.65166900    3.83101900
 C                  2.36482300   -1.78361000    4.59060600
 H                  3.63390700   -2.90912800    3.25549800
 H                  0.87330200   -0.66125700    5.67490700
 H                  3.07942500   -1.78466200    5.40893900
 C                 -4.16684400   -1.63241500    0.39697900
 C                 -4.87204000   -1.81478600   -0.81098700
 C                 -4.87664500   -1.17526000    1.52606200
 C                 -6.23533700   -1.54388200   -0.88997000
 H                 -4.34237400   -2.19615600   -1.67893400
 C                 -6.24050000   -0.90842200    1.44476600
 H                 -4.36782900   -1.04372900    2.47530200
 C                 -6.92486200   -1.08819600    0.23806300
 H                 -6.76234900   -1.69414400   -1.82788600
 H                 -6.77331600   -0.56215100    2.32567500
 H                 -7.98950800   -0.88031000    0.17968100

C H P O S 0
6-31G*
****
Pd 0
lanl2dz
****

Pd 0
lanl2dz


