%mem=15000MB
#p opt=(calcfc,ts,noeigentest) freq b3lyp/genecp scrf=(solvent=dichloromethane,pcm)

Title Card Required

1 1
 Pd                -0.57946500   -1.22466600   -0.52543300
 C                 -0.72931000   -3.38675600   -1.08300500
 C                  0.62231100   -2.94252800   -1.03343200
 C                 -1.45739200   -3.40202000   -2.30676700
 H                 -1.18590900   -3.83418600   -0.20335400
 P                  0.93628800    0.36328800    0.20269300
 O                  0.26471800    1.78159100    0.68335700
 O                  1.95456800    0.21036600    1.51089600
 O                  1.94098400    0.81122800   -1.01229300
 C                  3.01540200   -0.69975700    1.38705700
 C                  3.09530200    1.59904100   -0.83802400
 C                  4.04040800   -0.33706500    0.49402300
 C                  3.05134600   -1.86841800    2.16916000
 C                  4.11280000    1.07228400   -0.02263600
 C                  3.21433000    2.81179600   -1.54053700
 C                  5.03701400   -1.28544300    0.17387600
 C                  4.09130900   -2.75565800    1.85525100
 C                  2.09869600   -2.13360200    3.35913800
 C                  5.22778700    1.88528500    0.28699900
 C                  4.36405000    3.55541900   -1.24068200
 C                  2.22170700    3.28469900   -2.62956100
 C                  5.03799700   -2.51882800    0.85407900
 H                  4.17307300   -3.68470700    2.40668600
 C                  0.64861000   -2.38679900    2.89102100
 C                  2.53608100   -3.37159500    4.17196600
 C                  2.13170200   -0.92086900    4.32293800
 C                  5.33650600    3.14773000   -0.32491300
 H                  4.51510300    4.50918500   -1.73096500
 C                  2.71234500    4.57338300   -3.32519600
 C                  0.82677100    3.59025600   -2.03958100
 C                  2.09772400    2.19497800   -3.72419600
 H                  0.24091000   -1.54465800    2.32823700
 H                  0.59204800   -3.27717900    2.25392800
 H                  0.00269900   -2.55704900    3.76156800
 H                  2.47774800   -4.29589100    3.58623700
 H                  3.55672400   -3.27032600    4.55702900
 H                  1.86667700   -3.48671600    5.03146700
 H                  3.14804200   -0.75142300    4.69718600
 H                  1.78837500   -0.00467500    3.83809400
 H                  1.48350500   -1.11504200    5.18604400
 C                  6.50583100    4.05880100   -0.02737700
 H                  2.00204300    4.84175000   -4.11488300
 H                  2.76890100    5.42195300   -2.63422700
 H                  3.69407300    4.44299200   -3.79383900
 H                  0.17272600    3.98467500   -2.82718600
 H                  0.35779800    2.70101500   -1.62028800
 H                  0.89275800    4.34393300   -1.24636700
 H                  3.07163900    1.99623900   -4.18686900
 H                  1.71107000    1.25607700   -3.32120000
 H                  1.41465700    2.53618800   -4.51169700
 C                  6.07808300   -3.57294800    0.54927200
 C                  6.08521700   -1.02399500   -0.88395300
 H                  7.09023100   -0.94520900   -0.44929600
 H                  6.11944500   -1.85257200   -1.60123400
 H                  5.88779900   -0.10634500   -1.43994900
 C                  6.29150300    1.45816100    1.27394300
 H                  6.02023000    0.54747100    1.80863000
 H                  7.25628500    1.28328800    0.78006700
 H                  6.46007100    2.24645700    2.01699500
 H                  6.52765600    4.36023200    1.02806300
 H                  7.46691300    3.57156700   -0.23456800
 H                  6.45524000    4.96972200   -0.63115600
 H                  7.09810100   -3.18819400    0.67367800
 H                  5.96343800   -4.43764400    1.20951400
 H                  6.00222100   -3.93126600   -0.48568800
 S                 -2.57685700    0.36929700   -0.64210000
 C                 -2.20689700    1.92680200    0.35893700
 H                 -1.89583400    2.62381700   -0.42855800
 C                 -1.01949200    1.73962300    1.33668300
 H                 -1.13513900    0.78534900    1.85969300
 C                 -1.15027700    2.88990800    2.34679300
 H                 -0.71549000    2.64173700    3.31983300
 H                 -0.61898100    3.77033700    1.96062600
 C                 -3.26071800    2.57491200    1.23478500
 C                 -2.64157300    3.12528600    2.37229900
 C                 -4.62876100    2.75556000    1.02525200
 C                 -3.38748000    3.82610000    3.31776000
 C                 -5.37488600    3.45900400    1.97652300
 H                 -5.11965200    2.35321300    0.14780000
 C                 -4.76223500    3.98513900    3.11800800
 H                 -2.90651300    4.24581200    4.19743100
 H                 -6.44198600    3.59426800    1.82452200
 H                 -5.35574700    4.52481700    3.85071400
 H                  1.20046400   -3.18997300   -0.14703300
 C                  1.42739100   -2.70167700   -2.30978600
 H                  1.68237100   -1.63902100   -2.39495100
 H                  2.38537000   -3.23060200   -2.22465400
 C                 -0.80520200   -2.85913100   -3.55580800
 H                 -1.30868900   -3.25136400   -4.44475700
 H                 -0.96840700   -1.77200800   -3.56649400
 C                  0.69835600   -3.17128100   -3.58315800
 H                  1.15440600   -2.71222000   -4.46646100
 H                  0.82986300   -4.25470200   -3.69618500
 H                 -2.54111200   -3.38816500   -2.25817700
 N                 -1.56030700   -5.43769100   -2.81212000
 H                 -1.98535300   -5.91637900   -2.01922600
 H                 -2.12241300   -5.62765900   -3.64197000
 H                 -0.62921600   -5.82610200   -2.95387000
 C                 -4.26672400   -0.19750100   -0.30422000
 C                 -4.60158700   -0.83646100    0.91575900
 C                 -5.22731200   -0.03083600   -1.34284900
 C                 -5.92763100   -1.25552400    1.10091800
 C                 -6.53217800   -0.48078200   -1.09207500
 C                 -6.88905900   -1.07337700    0.11587800
 H                 -6.20508000   -1.73695300    2.03389300
 H                 -7.28411200   -0.36041900   -1.86718900
 H                 -7.91149900   -1.40175500    0.28104200
 C                 -4.98995600    0.56112000   -2.74211900
 H                 -5.97045700    0.49690900   -3.22913400
 C                 -3.60646900   -1.13896800    2.03247200
 H                 -2.63234500   -0.74429600    1.73523800
 C                 -4.04269900   -0.28523800   -3.61741600
 H                 -4.34709600   -1.33826600   -3.61913100
 H                 -4.07737500    0.07630700   -4.65207800
 H                 -3.00557400   -0.22648500   -3.27665900
 C                 -4.61774300    2.05646600   -2.77575900
 H                 -5.34198800    2.65832100   -2.21579800
 H                 -3.62140700    2.24828400   -2.36978700
 H                 -4.62804800    2.40803800   -3.81430200
 C                 -3.99574400   -0.47524500    3.36756900
 H                 -3.22466000   -0.67339300    4.12146000
 H                 -4.10064500    0.60846600    3.26197900
 H                 -4.94217200   -0.87104400    3.75392200
 C                 -3.43159300   -2.66095800    2.21118500
 H                 -2.66280000   -2.86632100    2.96511800
 H                 -4.36111000   -3.13774100    2.54283800
 H                 -3.12502100   -3.13651400    1.27292200

C H P N O S 0
6-31G*
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Pd 0
lanl2dz
****

Pd 0
lanl2dz

