%nproc=12
%mem=21000MB
#p opt freq b97d scrf=(solvent=benzene,SMD) gen  
pseudo=read scfcyc=300  

TS3_insertion  Energy= -939.494458133

+1 1
 Au                -0.26678400   -0.38176200   -0.79584100
 C                  2.98601800   -1.28354000   -1.33637600
 H                  2.55190900   -0.31906500   -1.07279800
 C                  4.13268500   -1.76048000   -0.49828900
 O                  4.51923500   -0.78696500    0.36564200
 O                  4.66018200   -2.87299700   -0.59378600
 H                  2.35571300   -3.37362100   -1.58897100
 C                  5.62637700   -1.13008600    1.23979400
 H                  5.34932800   -1.96552600    1.89875500
 H                  5.82360600   -0.22272000    1.82219600
 H                  6.50939300   -1.40838800    0.64694800
 C                 -0.95503100    0.59875500    0.81786400
 C                 -2.33647000    1.31473300    2.45522000
 C                 -1.15323600    1.99563600    2.57947500
 H                 -3.25605200    1.35445400    3.02655000
 H                 -0.82818600    2.75535400    3.28015200
 N                 -2.19014800    0.46509000    1.36734200
 N                 -0.32029600    1.53390600    1.56842900
 C                  2.07099700   -2.36188100   -1.88119900
 C                  0.63042100   -2.13353200   -2.13899800
 C                  3.06431000   -1.60841500   -2.82554200
 C                  0.19661600   -1.12519300   -3.00806100
 H                 -0.05232800   -2.95187800   -1.89564100
 C                  2.47707000   -0.64975100   -3.77432000
 H                  3.96078900   -2.15072600   -3.13372000
 C                  1.15044500   -0.33854500   -3.78547100
 H                 -0.84255000   -1.13521100   -3.35234400
 H                  3.14577600   -0.20421000   -4.51378800
 H                  0.75877400    0.39642500   -4.48840500
 C                  1.01709600    1.98367200    1.26578600
 C                  1.18466500    2.82357200    0.14657300
 C                  2.08677600    1.51004500    2.06304100
 C                  2.49852600    3.23243300   -0.15242600
 C                  3.37527300    1.95448900    1.72061800
 C                  3.57976900    2.80963700    0.62831400
 H                  2.66639100    3.89027400   -1.00598500
 H                  4.22987600    1.61996800    2.30670400
 H                  4.59075200    3.13847000    0.38080500
 C                 -3.17218100   -0.43188700    0.80388000
 C                 -4.01059300    0.06968800   -0.21409300
 C                 -3.14240600   -1.78528400    1.20206000
 C                 -4.88652300   -0.84535500   -0.82621100
 C                 -4.04228600   -2.65704100    0.56113900
 C                 -4.90626400   -2.19276100   -0.43982400
 H                 -5.55108100   -0.49697500   -1.61798000
 H                 -4.05288400   -3.71062300    0.84339200
 H                 -5.59457000   -2.88629500   -0.92659200
 C                 -3.94683700    1.51966500   -0.68658000
 H                 -3.29845100    2.08732300   -0.00299700
 C                 -2.15576900   -2.31656300    2.23756000
 H                 -1.58984800   -1.47084000    2.65436300
 C                 -5.33650100    2.19060000   -0.67005900
 H                 -5.24686800    3.24738100   -0.96924600
 H                 -6.02605000    1.69831800   -1.37379900
 H                 -5.78676400    2.14981100    0.33457100
 C                 -3.31421600    1.59950200   -2.09453000
 H                 -3.26357000    2.64871000   -2.42826400
 H                 -2.29393600    1.18425600   -2.09512200
 H                 -3.91728500    1.03488900   -2.82434300
 C                 -2.88147500   -3.01642100    3.40730300
 H                 -3.60311700   -2.33934100    3.89189300
 H                 -3.42895600   -3.90677200    3.05964700
 H                 -2.14861800   -3.34332600    4.16247900
 C                 -1.13997100   -3.27403200    1.57484700
 H                 -0.57593800   -2.76471600    0.77777000
 H                 -0.42277500   -3.64614400    2.32390600
 H                 -1.65557100   -4.14164400    1.13183700
 C                  0.02112200    3.30330100   -0.71640000
 H                 -0.89271300    2.77166800   -0.41672500
 C                  1.85662200    0.48852700    3.17692900
 H                  0.89069500    0.71080100    3.65625600
 C                  2.93265900    0.51933900    4.27822100
 H                  3.06823400    1.53332500    4.68682800
 H                  2.63593100   -0.15018800    5.10054100
 H                  3.90500900    0.16540900    3.89920800
 C                  1.75759800   -0.93492900    2.57327800
 H                  0.97038700   -0.99833800    1.80899300
 H                  2.71191800   -1.20972700    2.09938900
 H                  1.53403500   -1.66727500    3.36618000
 C                  0.26140000    2.98667500   -2.20714400
 H                  0.45956600    1.91364100   -2.35794300
 H                 -0.62438200    3.26695300   -2.79885000
 H                  1.12363800    3.54905000   -2.59969600
 C                 -0.22721100    4.81352500   -0.50629000
 H                 -1.07784600    5.14767600   -1.12281800
 H                 -0.45396700    5.03684300    0.54876800
 H                  0.65943600    5.39985500   -0.79644200

-Si -C -N -O -H 
6-31g(d)
*****
-Au 0
lanl2dz 
F  1  1.0
1.050    1.0000
*****

-Au 0    
lanl2dz  
 
 


