%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(pcm,solvent=n,n-dimethylformamide) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

Opt freq

-1 1
 C                 -2.50708291    2.64994124    1.69273765
 C                 -1.60132788    2.32710618    0.62489692
 C                 -1.93461676    2.66099773   -0.67434934
 C                 -3.17541543    3.34769090   -0.95578955
 C                 -4.04551277    3.68892896    0.08254125
 C                 -3.70339728    3.33390325    1.44073085
 C                 -2.48469418    1.56491612    2.65912740
 C                 -1.57013823    0.56326622    2.18597093
 C                 -0.78158137    1.08601746    0.98849798
 C                 -0.81028722    0.08641619   -0.13455168
 C                 -1.69642907    1.71108995   -1.77558637
 C                 -3.70611041    2.83720153   -2.21258917
 C                 -5.08279846    2.67908809   -2.37576293
 C                 -5.98744312    3.01889975   -1.28769991
 C                 -5.47847474    3.51186828   -0.08415116
 C                 -6.02167826    3.04877356    1.18012975
 C                 -4.92282005    2.93764648    2.12657835
 C                 -4.90057655    1.89644019    3.05324006
 C                 -3.65532511    1.20062819    3.33570227
 C                 -1.86233382   -0.77077264    2.36537750
 C                 -3.07207432   -1.16617330    3.04416563
 C                 -3.95793322   -0.20053666    3.53094696
 C                 -5.38545788   -0.38247563    3.36824176
 C                 -5.97134635    0.91153001    3.06971156
 C                 -7.02335614    1.01517643    2.15688545
 C                 -7.04955531    2.10421859    1.19419337
 C                 -7.57824303    1.58921083   -0.05698402
 C                 -7.05631907    2.04055478   -1.27525733
 C                 -2.79157011    1.83009199   -2.71728556
 C                 -6.19448892   -1.26323633   -2.67920095
 C                 -5.02936241   -0.88354105   -3.34060407
 C                 -3.77899477   -1.57575264   -3.06754216
 C                 -3.74258132   -2.61230385   -2.12573975
 C                 -4.95791315   -3.00597866   -1.43445647
 C                 -7.05791430   -2.01756587   -0.63281370
 C                 -7.64982066   -0.72060898   -0.91539785
 C                 -7.11408422   -0.25274389   -2.18079759
 C                 -6.82197960    1.10096853   -2.35732982
 C                 -5.60161572    1.49713026   -3.04163705
 C                 -4.72365070    0.52613949   -3.52750080
 C                 -2.71208263   -0.60213247   -3.09160014
 C                 -1.66238193   -0.71262239   -2.17581843
 C                 -1.63295484   -1.79708009   -1.22146540
 C                 -2.63117647   -2.74404254   -1.22408677
 C                 -4.63166766   -3.39359628   -0.09256089
 C                 -5.46827108   -3.04656462    0.94727132
 C                 -6.70758084   -2.35444546    0.67728314
 C                 -7.87433151    0.18300866    0.12526091
 C                 -7.52524121   -0.17456652    1.49315251
 C                 -6.94844416   -1.41592290    1.76117078
 C                 -5.85797738   -1.52901790    2.71365745
 C                 -4.94003900   -2.53735135    2.22974865
 C                 -3.57174903   -2.35105408    2.37000392
 C                 -2.63368357   -2.70079744    1.31237968
 C                 -1.63522802   -1.74224057    1.27480883
 C                 -1.07470836   -1.26224638    0.04138361
 C                 -3.29023390    0.69722611   -3.37380041
 C                 -1.15689731    0.46381758   -1.49769560
 C                 -6.16481652   -2.35133000   -1.71541149
 C                 -3.08815557   -3.47118357    0.07092856
 C                 -2.61860717   -4.87121917    0.10121392
 N                 -2.24527561   -5.97044143    0.13371383
 C                  3.28366651   -3.32548881    0.27587619
 C                  4.71091313   -3.48961429    0.10610926
 C                  5.60255485   -3.11783225    1.11991793
 C                  5.08571613   -2.52553165    2.33990231
 C                  3.71083197   -2.33980765    2.50393087
 C                  2.77953475   -2.74054159    1.45319560
 C                  2.72895399   -2.91756722   -1.00113550
 C                  3.80947694   -2.85470229   -1.97244481
 C                  5.03949649   -3.20776907   -1.28513053
 C                  6.22834638   -2.55256517   -1.60519903
 C                  6.83531185   -2.42857265    0.78187666
 C                  6.01218077   -1.48702808    2.76889474
 C                  5.52950272   -0.31476424    3.35561995
 C                  4.10026036   -0.12835724    3.52918945
 C                  3.20982884   -1.12275286    3.10553439
 C                  1.97776989   -0.76566757    2.42706380
 C                  1.69384596   -1.79711231    1.42004324
 C                  1.19241699   -1.36599545    0.17851883
 C                  1.70533297   -1.97175117   -1.05162031
 C                  3.81634953   -1.85622118   -2.94840748
 C                  2.74314793   -0.87592412   -2.99659444
 C                  1.71296161   -0.93994844   -2.05944115
 C                  1.20372508    0.28044623   -1.43019360
 C                  0.83344016   -0.01135585   -0.08616228
 C                  0.85633719    1.04408986    0.98860438
 C                  1.67258953    0.56583599    2.20073688
 C                  2.61285245    1.57960924    2.59164714
 C                  3.79285758    1.25806126    3.27419178
 C                  7.09642719   -1.42839626    1.80721096
 C                  6.12338015    3.00452463    0.99810468
 C                  7.15697096    2.06602832    1.04286161
 C                  7.66453212    1.48486385   -0.18851550
 C                  7.11930792    1.86742814   -1.41734918
 C                  6.04254988    2.83790992   -1.46236721
 C                  4.12681712    3.58353986   -0.10163420
 C                  3.80817629    3.30096605    1.27692222
 C                  5.04183160    2.94096025    1.96509484
 C                  5.03473572    1.94504061    2.93936575
 C                  6.10858106    0.96893058    2.98900910
 C                  7.14932464    1.02662498    2.05900770
 C                  7.97674887    0.08972304    0.06815447
 C                  7.71949981   -0.87065104   -0.91514250
 C                  7.16035291   -0.47450769   -2.19563060
 C                  6.85816625    0.86616980   -2.44166343
 C                  5.63287724    1.22819798   -3.13174145
 C                  5.12084712    2.43865744   -2.51670602
 C                  3.74575194    2.60948734   -2.33744789
 C                  3.24065586    3.18881533   -1.11173119
 C                  2.62097908    2.61993419    1.57483910
 C                  1.68619251    2.25954913    0.54610973
 C                  2.00089578    2.51204662   -0.77816760
 C                  1.71600264    1.52903127   -1.83185690
 C                  2.80905937    1.57448035   -2.76687018
 C                  3.30961087    0.40592936   -3.37310267
 C                  4.73621317    0.22907706   -3.53159070
 C                  5.05364655   -1.17034261   -3.27821820
 C                  6.23562071   -1.51292243   -2.62210041
 C                  7.65175123   -0.19523944    1.45456605
 C                  7.14818317   -2.15526775   -0.55099557
 C                  5.55612892    3.40296444   -0.28141105


