%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

1 1
 C                 -1.24220500   -1.08440800    2.06046600
 H                 -0.81901300   -0.09588600    1.83271000
 N                 -1.46142700   -1.29600200    3.37279500
 O                 -1.47224600   -1.90110400    1.15899300
 O                  1.38247500   -2.85398500    0.16824400
 C                  1.33486600   -3.13666900    1.37059900
 H                  0.93497200   -4.10263300    1.71702800
 N                  1.73681900   -2.34185600    2.37916300
 O                 -2.07461300   -0.65573800   -2.26158900
 C                 -2.35554900    0.52858900   -2.47707100
 H                 -2.30430200    0.95243100   -3.49371300
 N                 -2.73468300    1.43133800   -1.55215300
 O                  0.33816400    0.32892200   -0.32900700
 C                  0.43851800    1.35765200   -1.00987600
 H                  0.38665900    1.32348400   -2.10822500
 N                  0.60938500    2.60018000   -0.52422100
 O                  0.83385500   -1.75672700   -3.00237300
 C                  0.50552800   -0.96878800   -3.89827500
 H                 -0.46484000   -1.05137700   -4.40966500
 N                  1.25065300    0.06826300   -4.33140000
 Na                -0.41053400   -1.85735100   -1.00711300
 C                  2.28412100   -1.01477100    2.11654700
 H                  1.93057700   -0.66096100    1.14838500
 H                  1.94196600   -0.32697900    2.89619000
 H                  3.38076100   -1.03744900    2.12947100
 C                  1.73051100   -2.80547300    3.75952500
 H                  2.75109500   -2.84847100    4.15710500
 H                  1.14159700   -2.12432400    4.38238800
 H                  1.28821300   -3.80288700    3.81421600
 C                 -1.23815100   -0.24956700    4.36120300
 H                 -2.18180000    0.02439700    4.84709400
 H                 -0.53819700   -0.59364800    5.13091200
 H                 -0.82063200    0.63573400    3.87574000
 C                 -2.00636500   -2.56077400    3.84949100
 H                 -2.99457600   -2.40493800    4.29740400
 H                 -2.09193800   -3.24470700    3.00567200
 H                 -1.34225000   -2.99206400    4.60656400
 C                  0.72173700    2.84147700    0.90953000
 H                 -0.12846500    3.43663900    1.26184900
 H                  0.73824100    1.88457700    1.43052800
 H                  1.64640100    3.38883600    1.12194600
 C                  0.70803400    3.75828700   -1.40338800
 H                 -0.06108000    4.49483000   -1.14596000
 H                  1.69165100    4.23090100   -1.30385100
 H                  0.56460500    3.44985500   -2.44170700
 C                  0.80563600    0.93156200   -5.41767000
 H                  1.49759500    0.86657900   -6.26514600
 H                 -0.18983100    0.62811300   -5.75016200
 H                  0.76360300    1.97308100   -5.07925600
 C                  2.57016700    0.33330800   -3.77070900
 H                  2.62903300    1.37361200   -3.43218200
 H                  2.73527200   -0.33647000   -2.92730000
 H                  3.34495100    0.16834600   -4.52835500
 C                 -2.88774800    1.06595300   -0.15010500
 H                 -3.90194500    1.30874700    0.18612300
 H                 -2.70285900    0.00003400   -0.03303400
 H                 -2.17026200    1.62321200    0.46245400
 C                 -3.00532600    2.81840700   -1.90458400
 H                 -4.04354400    3.07796400   -1.66867300
 H                 -2.34208500    3.48404800   -1.34090800
 H                 -2.83419300    2.97347600   -2.97229900
 O                 -1.54035200   -3.90725100   -1.27260300
 C                 -1.65401300   -4.58892400   -0.24570900
 H                 -2.48097800   -4.42840100    0.46187000
 N                 -0.81709800   -5.57500700    0.13115500
 C                 -1.01727600   -6.31618500    1.36901300
 C                  0.33889200   -5.93115600   -0.68307200
 H                 -1.15656800   -7.38263900    1.15843200
 H                 -0.14800700   -6.20388800    2.02794900
 H                 -1.90069500   -5.93891400    1.88962400
 H                  0.35817600   -7.01488300   -0.83900800
 H                  0.26109600   -5.42098400   -1.64240700
 H                  1.26631500   -5.62199500   -0.18986800

