%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

1 1
 C                 -1.64397000   -0.22299700    2.41607900
 H                 -1.56396400    0.81862500    2.07269700
 N                 -1.46148100   -0.36820900    3.74182700
 O                 -1.86637300   -1.14577800    1.62018200
 O                  1.02093200   -2.29935100    1.00765700
 C                  1.42068900   -2.52303000    2.15628700
 H                  1.45696700   -3.54797600    2.55937100
 N                  1.84421700   -1.59551000    3.03493500
 O                 -2.32302200   -1.16867600   -1.87054900
 C                 -2.87948500   -0.25591000   -2.49766800
 H                 -3.04165800   -0.33156800   -3.58522700
 N                 -3.34323400    0.89040900   -1.97299400
 O                  0.01468400    0.93900500    0.00359000
 C                  0.94613500    1.50860600   -0.58660400
 H                  1.30222300    1.14865400   -1.56186200
 N                  1.61471400    2.57777300   -0.12223900
 O                  0.86763100   -1.23626100   -2.19822700
 C                  0.50720400   -1.15705600   -3.38176400
 H                 -0.50119300   -1.46965300   -3.69013800
 N                  1.26301600   -0.69224100   -4.39243500
 Na                -0.56792400   -1.32983100   -0.34565500
 C                  1.89537500   -0.18216200    2.67758200
 H                  1.26563500    0.00166400    1.80909100
 H                  1.53390900    0.41675400    3.51863200
 H                  2.92549100    0.12062100    2.45173700
 C                  2.40540800   -1.97236800    4.32645100
 H                  3.46701200   -1.70290800    4.37508400
 H                  1.87747000   -1.45420500    5.13426500
 H                  2.30739300   -3.05001100    4.47627000
 C                 -1.25186500    0.77889500    4.61419700
 H                 -2.07091000    0.86406000    5.33772900
 H                 -0.31135000    0.66965800    5.16570200
 H                 -1.20727600    1.69481900    4.02028100
 C                 -1.50316900   -1.68241800    4.36986000
 H                 -2.33329200   -1.73545700    5.08348400
 H                 -1.63635900   -2.43717200    3.59572600
 H                 -0.56672500   -1.86868600    4.90619200
 C                  1.29145200    3.16820700    1.17070200
 H                  1.09294200    4.23893600    1.05278600
 H                  0.40783100    2.67387100    1.57305100
 H                  2.13042000    3.04073400    1.86488900
 C                  2.72311000    3.16543300   -0.86313800
 H                  2.51427800    4.21733200   -1.08816600
 H                  3.64495800    3.10981300   -0.27291300
 H                  2.87129800    2.62466400   -1.80082600
 C                  0.75157100   -0.61217500   -5.75418200
 H                  1.37228800   -1.21264600   -6.42878600
 H                 -0.27369700   -0.98775400   -5.78849100
 H                  0.76014600    0.42703100   -6.10269900
 C                  2.62279500   -0.21891500   -4.16478400
 H                  2.69329100    0.85179900   -4.39039400
 H                  2.88688900   -0.39067500   -3.12157000
 H                  3.31998700   -0.76018600   -4.81372900
 C                 -3.22751300    1.17284900   -0.54469200
 H                 -4.14372600    1.66453000   -0.20365400
 H                 -3.08362700    0.24106900    0.00184400
 H                 -2.36885600    1.82431800   -0.35033400
 C                 -3.90108100    1.94194700   -2.81449000
 H                 -4.92245800    2.17915900   -2.49698300
 H                 -3.29189700    2.85019700   -2.74027600
 H                 -3.92122500    1.61605400   -3.85705100

