%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

0 1
 C                 -3.16162000    0.07883500    1.07083300
 H                 -4.22787100    0.05348800    1.35244200
 N                 -2.61418000    1.30033900    1.13480700
 H                 -3.16898700    2.09761500    1.41282900
 H                 -1.63575500    1.43887800    0.87730700
 O                 -2.56333100   -0.94895000    0.73357900
 O                 -0.84251800   -1.11901100   -2.00244400
 C                 -1.16641300   -0.17200100   -2.72883600
 H                 -1.66662900   -0.34046400   -3.69763400
 N                 -0.94878900    1.12095200   -2.45048300
 H                 -1.25925300    1.83811100   -3.09104400
 H                 -0.51092000    1.39419500   -1.56641400
 O                  0.15041200    1.41920200    0.18457600
 C                  1.16520500    1.87478300    0.75223100
 H                  1.66846600    2.77369200    0.36682900
 N                  1.71660500    1.34029300    1.83526900
 H                  2.54798700    1.75511000    2.23423900
 H                  1.33326300    0.46772600    2.23759900
 O                  1.91869300   -1.31477800   -0.44969500
 C                  2.25885400   -0.50115000   -1.31189100
 H                  1.69008400   -0.36875900   -2.24485800
 N                  3.32860400    0.30513400   -1.20955300
 H                  3.56956300    0.95778500   -1.94238100
 H                  3.89959600    0.28131200   -0.37382600
 Na                -0.30189700   -1.34806200    0.28647300
 C                  0.14164100   -2.28062800    2.75603000
 N                  0.53165300   -1.16927900    2.71849100

