%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

0 1
 C                 -0.25879200   -1.98939200    0.55315500
 H                  0.51305800   -2.67710700    0.92917500
 N                 -0.24128200   -1.83849500   -0.78497600
 O                 -1.03435300   -1.40640400    1.32328200
 O                 -1.75380000    1.73102200    2.05873100
 C                 -1.89324100    1.93368200    0.84276400
 H                 -1.02589800    2.13043500    0.19707200
 N                 -3.06637500    1.91730700    0.18358900
 O                  1.09294000    1.01795900    0.63726000
 C                  2.02806000    0.40927100    0.09633300
 H                  2.56351200   -0.39125500    0.62784900
 N                  2.47337700    0.63219300   -1.15544500
 Na                -0.02526000    0.29281100    2.60297300
 C                  1.85279100   -1.19712100    3.19548400
 N                  2.59974100   -1.96351700    2.70668800
 C                 -4.31835800    1.63316400    0.87381000
 H                 -4.79044100    0.74415200    0.44063100
 H                 -4.10505300    1.45758600    1.92779100
 H                 -5.00556700    2.48078200    0.77300400
 C                 -3.13994500    2.16920000   -1.24931100
 H                 -3.56727400    1.30165400   -1.76542000
 H                 -3.77152700    3.04182000   -1.45064600
 H                 -2.13962000    2.35779800   -1.64604000
 C                  1.88470700    1.66416200   -1.99953900
 H                  1.04194000    2.11358400   -1.47475800
 H                  2.62758900    2.43766100   -2.22663500
 H                  1.53927300    1.22381900   -2.94148500
 C                  3.62261100   -0.08498100   -1.69236800
 H                  3.35819600   -0.57072000   -2.63839800
 H                  4.45323600    0.60641200   -1.87696300
 H                  3.94789300   -0.84947000   -0.98308300
 C                 -1.14320700   -0.90643400   -1.44715100
 H                 -0.57148600   -0.08234200   -1.88924900
 H                 -1.69612800   -1.41847100   -2.24202200
 H                 -1.84030000   -0.50861500   -0.71075200
 C                  0.71962900   -2.54003400   -1.62395400
 H                  0.20226500   -3.18624600   -2.34217200
 H                  1.32982900   -1.81914900   -2.17872000
 H                  1.37778000   -3.15274800   -1.00359600

