%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

0 1
 C                  0.54377900    1.39509400    0.14245600
 N                 -0.55443700    1.05800700   -0.11756200
 Na                 2.77965000    1.32460100    1.30424800
 C                  0.65914700    1.85293100    3.57337700
 N                  1.77123800    1.46392100    3.60139700
 Na                -1.49370500    1.52792800    2.32425100
 C                  1.90494100   -1.78256700    1.09132300
 N                  2.84364000   -1.27522400    1.59299100
 Na                -0.31252900   -1.50757200   -0.03639000
 C                 -0.89593400   -1.47713800    3.23127300
 N                 -1.90772500   -1.53102700    2.63224400
 Na                 1.48348100   -1.00242500    3.82866200
 C                  3.63999400    1.46027600   -1.60954100
 N                  4.26577000    1.04841700   -0.69972900
 Na                 1.39554800    1.36963800   -2.72813000
 C                  2.05637500   -1.68067800   -2.50899300
 N                  1.04403600   -1.50069000   -3.08204500
 Na                 3.89803100   -1.43152700   -0.83860200
 Na                -2.71827100    1.42277800   -1.16864900
 C                 -4.28708100    0.90279300    1.33477900
 N                 -3.62853500    1.85891300    1.12874000
 C                 -2.50506200   -1.62646600   -2.01671800
 N                 -2.80912100   -1.68229100   -0.88029700
 Na                -3.89469200   -1.60674900    1.29616100
 C                 -1.60495100    1.76629500   -3.37858100
 N                 -0.67559900    1.42423300   -4.01722000
 Na                -1.10681400   -1.08221100   -4.04034200

