%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

0 1
 C                 -0.07820700    2.40874700   -0.41696300
 N                 -1.05122400    2.07019600   -0.98999900
 Na                 1.82486700    1.40034200    0.91880400
 C                 -0.55163500    0.13629100    2.37232900
 N                  0.58312300   -0.17941200    2.41936500
 Na                -2.30287200    0.61968700    0.61240500
 C                  1.83618300   -0.45536800   -1.56958600
 N                  2.36753400   -0.56126700   -0.52263100
 Na                -0.48273100    0.10992800   -2.40115600
 C                 -1.21454500   -2.08564300   -0.42359300
 N                 -1.92965900   -1.30168400   -0.93696300
 Na                 0.96721400   -2.09435000    0.85232600

