%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

1 1
 C                  0.69079032    0.22143535   -0.02442921
 N                 -0.48224916    0.19252269    0.02300420
 Na                 3.07421398   -0.12693265    0.00195117
 Na                -3.14412287   -0.11636471   -0.00326518

