%nprocshared=8
%mem=22GB
#p opt=calcfc freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq calcfc

1 1
 O                  5.19523314   -0.92396983    0.11688216
 C                  6.38009876   -0.57987756    0.00876211
 H                  7.18404800   -1.32962680   -0.04691895
 N                  6.82871099    0.68326599   -0.05174051
 Na                -2.95708383   -1.04169393   -0.02834728
 C                 -0.50815556   -1.06196555   -0.00774629
 N                  0.66453962   -1.07409124    0.02698533
 C                  5.92119993    1.82305283    0.00860783
 H                  4.89983959    1.46653360    0.13626693
 H                  6.19076524    2.46767973    0.85225872
 H                  5.99143036    2.40676082   -0.91597618
 C                  8.24941705    0.98302597   -0.18680306
 H                  8.42889595    1.55130885   -1.10610673
 H                  8.59205440    1.57824265    0.66681259
 H                  8.82472992    0.05548461   -0.22628604
 Na                 2.97985057   -1.07910766    0.15585359
 O                 -5.16779024   -0.86921011   -0.05927683
 C                 -6.36981341   -0.57877010   -0.12889584
 H                 -7.13030957   -1.35550199   -0.30151680
 N                 -6.88643004    0.65359491   -0.00831242
 C                 -6.04100809    1.81803956    0.22612586
 H                 -5.00217037    1.49943291    0.30388757
 H                 -6.14506852    2.52846712   -0.60147968
 H                 -6.34193260    2.31454125    1.15508629
 C                 -8.32134680    0.89339792   -0.10997001
 H                 -8.69641807    1.33594494    0.81940356
 H                 -8.53039913    1.58158787   -0.93633100
 H                 -8.84553781   -0.04740462   -0.29152272


