%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

0 1
 C                 -1.21659800    1.66649200    2.06350100
 N                 -1.83319500    0.93821400    1.37234800
 Na                 0.97126500    2.55756300    3.00345200
 C                  0.41496200    0.09201000    4.74208300
 N                  1.45707000    0.62366800    4.59880300
 Na                -1.53375500   -0.87266800    3.47624600
 C                  1.79923600    0.83804000    0.62469000
 N                  2.51263200    1.32610600    1.42427500
 Na                -0.25714400   -0.19857800   -0.34184300
 C                  0.57207800   -2.11843900    1.94047300
 N                 -0.15441700   -2.37746600    1.05013700
 Na                 2.59232500   -0.85018900    2.85303900
 C                  0.16266300    4.74156200    1.05562800
 N                  1.26795400    4.55304900    1.41859800
 Na                -1.84740300    3.65304700    0.02322900
 C                  0.20611200    2.80183800   -1.97266500
 N                 -0.60787500    2.18525000   -2.56019200
 Na                 2.25286400    3.32179100   -0.55931000
 Na                -4.06033700    0.07787200    0.82326700
 C                 -3.57634600   -2.61738300    1.92281900
 N                 -3.68976600   -1.66223300    2.60408900
 C                 -2.78319400   -0.81888100   -2.23135000
 N                 -2.45403900   -1.73363600   -1.56659700
 Na                -2.09683700   -3.52449900    0.09444700
 C                 -4.43910500    2.14272900   -0.53927000
 N                 -3.84454700    2.91433100   -1.20279800
 Na                -2.86981500    1.53447800   -3.05120500
 C                  2.08558700   -1.36520900   -2.26647100
 N                  1.06145900   -1.45145400   -2.84251800
 Na                 3.90167300   -0.32007800   -0.83193000
 C                  3.73056400   -2.83169900    0.74812000
 N                  4.20962800   -1.83826500    1.16355600
 Na                 1.62666800   -3.79882300   -0.21179000
 C                  3.43513100    1.82171700   -2.94269500
 N                  3.96398700    1.98632500   -1.90206700
 Na                 1.25975600    0.92397400   -3.85625800
 Na                -0.90691400   -2.64210100   -3.50222000
 C                 -0.56909100   -4.71373100   -2.14935200
 N                 -0.31369100   -5.04514000   -1.04768400

