%nprocshared=24
%mem=41GB
#p opt=(maxstep=9,calcfc) freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq with calcfc

-1 1
 C                  0.78043402    0.55065726    2.84204740
 N                 -0.35777465    0.36023640    2.60840126
 Na                 3.26725722    0.36420513    2.53399440
 C                  2.40390782   -2.44304605    3.41896085
 N                  3.39907640   -2.14692448    2.85954162
 Na                -0.10993299   -2.23278093    3.30313358
 C                  2.34002534   -0.19703469   -0.14062085
 N                  3.51692087   -0.19638642   -0.11884348
 Na                -0.14564672    0.01038638   -0.00048405
 C                  0.40811658   -3.17281297    0.59777706
 N                 -0.75134757   -3.03380462    0.45188357
 Na                 2.91720692   -2.91804881    0.46282883
 C                  2.84767472    3.34307675    2.18131999
 N                  3.80983139    2.81520049    1.74933085
 Na                 0.31768662    3.36822137    2.18544885
 C                  0.83043944    2.98738075   -0.62879685
 N                 -0.32299004    3.01385865   -0.39520468
 Na                 3.26996902    2.41793396   -0.74618892
 Na                -2.73464794    0.46440097    3.01076172
 C                 -3.19115435   -2.62764782    2.97578001
 N                 -2.56512626   -1.96365764    3.72466832
 C                 -3.37597017    0.81712174    0.14135153
 N                 -3.41719634   -0.35531573    0.23283051
 Na                -3.13891381   -2.74300695    0.40437680
 C                 -2.65734026    2.99981053    2.92914985
 N                 -2.12335055    3.92017998    2.42027439
 Na                -2.77124784    3.22565989   -0.10824692
 C                  0.31964982   -0.63817342   -2.95435732
 N                 -0.73546039   -0.31080890   -2.54558451
 Na                 2.82187856   -0.83363606   -2.90842991
 C                  2.01983933   -3.69422062   -2.41793202
 N                  3.07846657   -3.25394658   -2.14095482
 Na                -0.48636078   -3.37544717   -2.17907867
 C                  2.35234915    2.12379956   -3.65894683
 N                  3.36791036    1.67381905   -3.26238875
 Na                -0.13824828    2.26113583   -3.23823745
 Na                -3.13092429    0.00345283   -2.70879248
 C                 -3.45944593   -2.51231356   -2.60219690
 N                 -3.00158487   -3.47844165   -2.10411816
 C                 -3.02398204    3.10797681   -2.67639982
 N                 -2.59538827    2.38389338   -3.50337324

