%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

0 1
 O                 -1.96372200    0.08955800   -0.00842700
 C                 -0.86589900    0.64445100   -0.00472600
 H                 -0.76614300    1.74544200   -0.00443700
 N                  0.33800400    0.02287500   -0.00082000
 C                  1.58771700    0.76641300    0.00465300
 H                  2.17626300    0.52265800    0.89754000
 H                  2.18507400    0.52049400   -0.88173200
 H                  1.38271700    1.83996900    0.00230100
 C                  0.42949000   -1.42955600    0.00012300
 H                  0.96381100   -1.77667200    0.89267800
 H                 -0.57933200   -1.84250100   -0.00443100
 H                  0.97209200   -1.77721300   -0.88719100

