%nprocshared=8
%mem=22GB
#p opt freq=noraman b3lyp 6-31G(d) scrf=(pcm,solvent=n,n-dimethylformamide) empiricaldispersion=gd3 scf=(xqc,maxcyc=1024) nosymm

Opt freq

-1 1
 C                  0.40536300    3.26689400   -0.57629900
 N                 -0.42036500    3.09045500    0.25069000
 C                 -0.87879300   -0.43137100   -0.02611000
 H                 -0.83964100    0.67115000   -0.05209400
 N                  0.35569800   -0.99274900    0.02772000
 O                 -1.94267200   -1.05702600   -0.04131600
 C                  0.52284500   -2.43594800    0.07914900
 H                  1.07008500   -2.72474100    0.98518000
 H                 -0.46259200   -2.90235400    0.08524100
 H                  1.08900600   -2.78796200   -0.79242600
 C                  1.56470100   -0.18169600    0.03483300
 H                  2.14016600   -0.36238500    0.95215100
 H                  2.20019900   -0.43963000   -0.82236900
 H                  1.30381900    0.87840800   -0.02332800

