%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(pcm,solvent=n,n-dimethylformamide) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

Opt freq

-1 1
 C                 -1.70985237    0.75957787    2.22397002
 C                 -1.17404226   -0.21271766    1.29662256
 C                 -0.68089275    0.16562879   -0.02888090
 C                 -1.14298177    1.53044093   -0.45928670
 C                 -1.67847701    2.45137346    0.42827189
 C                 -1.96255856    2.06516383    1.81127378
 C                 -2.65115498    0.07615488    3.09591744
 C                 -2.67912716   -1.31401661    2.68139029
 C                 -1.73521694   -1.47584858    1.57503870
 C                 -2.06647559   -2.37032232    0.51751138
 C                 -1.19957114   -0.72292233   -1.12003705
 C                 -1.63966313    1.47107481   -1.81031972
 C                 -2.63987244    2.35143723   -2.24530109
 C                 -3.19712108    3.31469500   -1.32060513
 C                 -2.73109811    3.35129976   -0.00248992
 C                 -3.66032723    3.52557822    1.09900435
 C                 -3.18622515    2.72822344    2.22002596
 C                 -4.10269375    2.06853133    3.04393343
 C                 -3.82586096    0.71343180    3.49264381
 C                 -3.87839000   -2.00882308    2.68307415
 C                 -5.09733529   -1.35663236    3.09874145
 C                 -5.07983050   -0.01886350    3.49606457
 C                 -6.13035378    0.88096724    3.05983003
 C                 -5.52744549    2.16854940    2.77304187
 C                 -5.98396312    2.94521747    1.70252969
 C                 -5.02901895    3.62780315    0.84732033
 C                 -5.51982714    3.57234969   -0.52260198
 C                 -4.62146934    3.41890191   -1.58312747
 C                 -1.67326560    0.07897679   -2.21957574
 C                 -6.17084248    0.42261276   -3.08270713
 C                 -4.99529041   -0.21009088   -3.48166231
 C                 -4.71364420   -1.57105308   -3.04540672
 C                 -5.61176778   -2.23324040   -2.19913125
 C                 -6.83784397   -1.57298941   -1.78246761
 C                 -7.67618918    0.68348264   -1.30204973
 C                 -7.08015057    1.97832769   -1.57535758
 C                 -6.14635462    1.81737413   -2.67683966
 C                 -4.94185255    2.52427417   -2.68102918
 C                 -3.71421796    1.86172869   -3.09161129
 C                 -3.74240128    0.52255663   -3.48769541
 C                 -3.29776558   -1.67523400   -2.78546820
 C                 -2.84799537   -2.43866782   -1.70223529
 C                 -3.79130498   -3.13737506   -0.85331005
 C                 -5.14265114   -3.06836703   -1.12848779
 C                 -7.16105718   -1.98096444   -0.44644425
 C                 -7.65933156   -1.05728221    0.45140414
 C                 -7.93252019    0.29819952    0.01890881
 C                 -6.76606093    2.83544012   -0.51723266
 C                 -7.04907773    2.44007448    0.85598207
 C                 -7.61995208    1.19277426    1.11358336
 C                 -7.15252203    0.38785592    2.23489923
 C                 -7.19138222   -1.00183732    1.84578608
 C                 -6.15951959   -1.85803974    2.23505415
 C                 -5.60182288   -2.85261520    1.35559214
 C                 -4.21751302   -2.91028536    1.57128154
 C                 -3.27165090   -3.11264604    0.52558874
 C                 -2.69313050   -0.38780362   -3.05565632
 C                 -1.77645956   -1.95378981   -0.86201441
 C                 -7.11887257   -0.27272907   -2.22628042
 C                 -6.22230815   -3.14240395   -0.01147452
 C                 -6.92894273   -4.44089689   -0.02435828
 N                 -7.48058783   -5.46334652   -0.02195118
 C                  4.33705517   -1.81417855    3.08088033
 C                  5.76396689   -1.57078412    3.01804805
 C                  6.27253625   -0.27658143    3.16674492
 C                  5.35836682    0.83473905    3.36064613
 C                  3.98082710    0.60964078    3.40493999
 C                  3.45021333   -0.74071844    3.26050836
 C                  4.01799335   -2.84241094    2.10693817
 C                  5.25091901   -3.25072303    1.45292720
 C                  6.33274042   -2.46171610    2.01668406
 C                  7.37330730   -2.02157568    1.19879645
 C                  7.35276091    0.18042797    2.30958584
 C                  5.88228224    1.98326500    2.63610904
 C                  5.00966814    2.86437432    1.99447998
 C                  3.57708234    2.63071899    2.04592746
 C                  3.07499270    1.52180343    2.73551828
 C                  1.98987546    0.73929233    2.17316314
 C                  2.21175201   -0.66605716    2.52212697
 C                  1.92439305   -1.64003887    1.55398867
 C                  2.83866056   -2.76396614    1.36673494
 C                  5.25076110   -3.56470393    0.09265558
 C                  4.01763395   -3.48442598   -0.67371833
 C                  2.83894376   -3.08829806   -0.04217685
 C                  1.92637149   -2.15931322   -0.70298397
 C                  1.34480522   -1.30431953    0.28744864
 C                  0.91881124    0.06295827   -0.02501726
 C                  1.44947997    1.08947978    0.94612219
 C                  1.98792619    2.21048377    0.22292198
 C                  3.01717774    2.98957757    0.76253711
 C                  7.11619971    1.57934042    1.98722692
 C                  5.33390044    2.72934302   -2.10476801
 C                  6.52021967    2.65305675   -1.37217517
 C                  7.42867211    1.53703723   -1.57514339
 C                  7.11596947    0.54244531   -2.50471057
 C                  5.88122193    0.62097126   -3.26348895
 C                  3.57613177    1.46060421   -3.01622468
 C                  3.01603680    2.34590304   -2.01955811
 C                  4.10125255    3.13468603   -1.45195467
 C                  4.10215966    3.44896936   -0.09380398
 C                  5.33519727    3.37081908    0.66998664
 C                  6.52064583    2.97955481    0.04424048
 C                  7.99311283    1.17685713   -0.28567524
 C                  8.21598101   -0.16697669    0.02449465
 C                  7.89628937   -1.20214403   -0.94343561
 C                  7.35270437   -0.85648618   -2.18170173
 C                  6.27231493   -1.64287112   -2.75141735
 C                  5.35769156   -0.72864581   -3.41186047
 C                  3.98018377   -0.95060423   -3.35413287
 C                  3.07420873    0.16234278   -3.14996300
 C                  1.98587949    1.88327613   -1.19368830
 C                  1.44455910    0.55779508   -1.35161727
 C                  1.98919295   -0.29516063   -2.30013234
 C                  2.21255007   -1.70993620   -2.00019034
 C                  3.45012947   -2.10120236   -2.63233765
 C                  4.33688466   -2.98707474   -1.99991981
 C                  5.76394851   -2.74102997   -2.05028254
 C                  6.33287631   -3.10303841   -0.76001260
 C                  7.37313377   -2.34854201   -0.21809162
 C                  7.42861621    2.06518030    0.71548180
 C                  7.89601098   -0.67300816    1.34803391
 C                  5.00868095    1.69387257   -3.07324566



