%nprocshared=24
%mem=41GB
#p opt freq=noraman b3lyp 6-31g(d) scrf=(pcm,solvent=n,n-dimethylformamide) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

Opt freq

-1 1
 C                 -1.68760402    2.16220363    1.00527512
 C                 -1.20785428    1.60348661   -0.23653897
 C                 -1.76947814    2.01741376   -1.43737205
 C                 -2.83627606    2.99659333   -1.44036938
 C                 -3.29436552    3.54802013   -0.24135887
 C                 -2.70492639    3.12228835    1.01134644
 C                 -1.68022741    1.11103888    2.00765762
 C                 -1.20630062   -0.09522260    1.37748707
 C                 -0.73844408    0.20457814   -0.00637863
 C                 -1.21736730   -0.75363804   -1.00162186
 C                 -2.07048170    1.03485679   -2.48134635
 C                 -3.78700008    2.63408892   -2.48354020
 C                 -5.15462202    2.82694119   -2.27928847
 C                 -5.63182342    3.38993572   -1.02622538
 C                 -4.71901673    3.73775380   -0.02721026
 C                 -5.00841451    3.43367595    1.36304112
 C                 -3.76203891    3.05085775    2.00784757
 C                 -3.75385161    2.04062060    2.96929254
 C                 -2.68654209    1.05375336    2.97717098
 C                 -1.75382416   -1.31604099    1.72279548
 C                 -2.80056293   -1.38730053    2.71134656
 C                 -3.26362695   -0.22646802    3.33709938
 C                 -4.68234099   -0.03911932    3.55739389
 C                 -4.99032567    1.35853701    3.32297047
 C                 -6.18767360    1.72715386    2.70343912
 C                 -6.19481983    2.78093257    1.70262195
 C                 -7.14444897    2.41531035    0.66436793
 C                 -6.86529627    2.71384024   -0.67396259
 C                 -3.31192827    1.42288475   -3.12550713
 C                 -7.23557929   -0.70617773   -2.01359143
 C                 -6.22594547   -0.63813153   -2.96975468
 C                 -5.15524002   -1.62480845   -2.97079241
 C                 -5.12761765   -2.63038574   -1.99542752
 C                 -6.18068030   -2.69960564   -0.99679525
 C                 -7.69263742   -1.20791053    0.23263878
 C                 -8.00199908    0.19503549    0.01723748
 C                 -7.71658996    0.50659724   -1.37271453
 C                 -7.15962885    1.74135086   -1.71168957
 C                 -6.10168983    1.81177693   -2.70687713
 C                 -5.64534419    0.64629843   -3.32617645
 C                 -3.92756598   -0.95479304   -3.32810016
 C                 -2.73529243   -1.32470898   -2.69859347
 C                 -2.72145957   -2.38092812   -1.70873965
 C                 -3.88857401   -3.04536427   -1.39705202
 C                 -5.62325776   -3.15856697    0.24326700
 C                 -6.04676423   -2.60277881    1.43343201
 C                 -7.10625223   -1.61762096    1.43415234
 C                 -7.71613536    1.13049135    1.01410215
 C                 -7.11969082    0.70129190    2.27165356
 C                 -6.81670171   -0.64605955    2.47224498
 C                 -5.57503800   -1.03334646    3.12444119
 C                 -5.09810694   -2.24799548    2.50678715
 C                 -3.73478727   -2.41241691    2.26735556
 C                 -3.22116521   -3.00697094    1.05293265
 C                 -2.06708763   -2.31414447    0.68418766
 C                 -1.73429672   -2.01420022   -0.67210380
 C                 -4.22357056    0.44837282   -3.54874659
 C                 -1.80033605   -0.31107365   -2.25842847
 C                 -7.22245589   -1.76261225   -1.01293684
 C                 -4.15920346   -3.63255974    0.01812512
 C                 -4.06573052   -5.10785326    0.01743903
 N                 -3.98244194   -6.26659021    0.02657020
 C                  4.30710213   -1.76532844    3.07311751
 C                  5.73274121   -1.51626366    2.99371352
 C                  6.23771167   -0.22089989    3.14330744
 C                  5.32167528    0.88602357    3.35519332
 C                  3.94592233    0.65553315    3.41642371
 C                  3.41969542   -0.69608834    3.27047315
 C                  3.97902345   -2.78843686    2.09724273
 C                  5.20477624   -3.18748022    1.42457400
 C                  6.29144437   -2.39859414    1.97939460
 C                  7.31969537   -1.94957644    1.15084604
 C                  7.30502115    0.24547688    2.27504167
 C                  5.83174387    2.04056392    2.63076165
 C                  4.94738410    2.92206616    2.00580459
 C                  3.51650581    2.68247858    2.07414409
 C                  3.02756445    1.56765334    2.76301913
 C                  1.93880304    0.78353825    2.20963843
 C                  2.17263187   -0.62182969    2.54702754
 C                  1.87449077   -1.59112674    1.57956357
 C                  2.78943578   -2.70944838    1.37246085
 C                  5.18805123   -3.49319203    0.06270211
 C                  3.94481794   -3.41316989   -0.68759528
 C                  2.77212288   -3.02556145   -0.03885390
 C                  1.84599860   -2.09838433   -0.68290187
 C                  1.27352294   -1.24963868    0.32159126
 C                  0.86253884    0.11609021    0.01721214
 C                  1.38057668    1.13764627    0.99017537
 C                  1.90453061    2.26909697    0.26796218
 C                  2.93864200    3.04691986    0.79942299
 C                  7.05880664    1.64528185    1.96390625
 C                  5.22088470    2.81378941   -2.09837233
 C                  6.41635411    2.73724980   -1.38103639
 C                  7.32618468    1.62572542   -1.60214518
 C                  7.00541340    0.63577837   -2.53398977
 C                  5.76090503    0.71427419   -3.27686912
 C                  3.45604750    1.54486287   -2.99657013
 C                  2.90568200    2.42217832   -1.98724738
 C                  3.99503739    3.21035455   -1.42763222
 C                  4.01117951    3.51591718   -0.06749997
 C                  5.25393597    3.43757932    0.68039750
 C                  6.43316058    3.05518372    0.03732957
 C                  7.90841153    1.26008558   -0.32225644
 C                  8.14025993   -0.08468508   -0.02287503
 C                  7.81155343   -1.11518378   -0.99260008
 C                  7.25092622   -0.76422172   -2.22174136
 C                  6.16618718   -1.55099063   -2.78205096
 C                  5.24037539   -0.63639211   -3.42631010
 C                  3.86451058   -0.86368090   -3.35217535
 C                  2.95690801    0.24493997   -3.13236950
 C                  1.88806778    1.95123182   -1.15074212
 C                  1.35385749    0.62333412   -1.30929197
 C                  1.88486798   -0.22143043   -2.27179114
 C                  2.11694541   -1.63709156   -1.97957967
 C                  3.34768545   -2.02025656   -2.63005363
 C                  4.24546732   -2.90687301   -2.01443628
 C                  5.67092965   -2.65548411   -2.08167928
 C                  6.25755855   -3.02285370   -0.80078185
 C                  7.30231728   -2.26801752   -0.26783407
 C                  7.35310392    2.14031098    0.69148247
 C                  7.83936101   -0.60005836    1.30165112
 C                  4.88703356    1.78291849   -3.06920651



